Through measuring the coefficient of linear expansion, the structure and properties of the Li2O-Al2O3-SiO2 low expansion glass ceramics containing B2O3 are studied by JR and XRD. It is shoutn that the IR method is eff...Through measuring the coefficient of linear expansion, the structure and properties of the Li2O-Al2O3-SiO2 low expansion glass ceramics containing B2O3 are studied by JR and XRD. It is shoutn that the IR method is efficient in the study of the glass-ceramics structure. There is a " Boron abnormality" in the system which has an important influence on the properties of the glass-ceramics.展开更多
Na2O-Al2O3-SiO2 glass-ceramics doped with Er^3+ ions were synthesized by the conventional melt quenching technique at a low melting temperature.The samples were characterized by differential scanning calorimetry(DSC...Na2O-Al2O3-SiO2 glass-ceramics doped with Er^3+ ions were synthesized by the conventional melt quenching technique at a low melting temperature.The samples were characterized by differential scanning calorimetry(DSC),X-ray diffraction(XRD),scanning electron microscopy(SEM),UV-vis-NIR scanning spectrophotometry,and fluorescence spectrometry.The results show that the main crystalline phase of glass-ceramics is nepheline.The best heat-treatment process is at 520 ℃ for 2 h.Because the up-conversion luminescence and near infrared luminescence properties of glass doped with Eu^3+ are studied in detail.展开更多
摘要Through measuring the coefficient of linear expansion, the structure and properties of the Li2O-Al2O3-SiO2 low expansion glass ceramics containing B2O3 are studied by JR and XRD. It is shoutn that the IR method is efficient in the study of the glass-ceramics structure. There is a " Boron abnormality" in the system which has an important influence on the properties of the glass-ceramics.
基金Funded by the National High Technology Research and Development Program of China(No.2011AA030204)Key Research Project of Jilin Provincial Science and Technology Department(No.20150204051GX)
摘要Na2O-Al2O3-SiO2 glass-ceramics doped with Er^3+ ions were synthesized by the conventional melt quenching technique at a low melting temperature.The samples were characterized by differential scanning calorimetry(DSC),X-ray diffraction(XRD),scanning electron microscopy(SEM),UV-vis-NIR scanning spectrophotometry,and fluorescence spectrometry.The results show that the main crystalline phase of glass-ceramics is nepheline.The best heat-treatment process is at 520 ℃ for 2 h.Because the up-conversion luminescence and near infrared luminescence properties of glass doped with Eu^3+ are studied in detail.