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The effects of radiation damage on power VDMOS devices with composite SiO_2-Si_3N_4 films 认领 引用 被引量:3
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作者 高博 刘刚 +5 位作者 王立新 韩郑生 宋李梅 张彦飞 腾瑞 吴海舟 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第3期393-398,共6页
Total dose effects and single event effects on radiation-hardened power vertical double-diffusion metal oxide semiconductor(VDMOS) devices with composite SiO2-Si3N4 film gates are investigated.The relationships amon... Total dose effects and single event effects on radiation-hardened power vertical double-diffusion metal oxide semiconductor(VDMOS) devices with composite SiO2-Si3N4 film gates are investigated.The relationships among the important electrical parameters of the samples with different thickness SiO2-Si3N4 films,such as threshold voltage,breakdown voltage,and on-state resistance in accumulated dose,are discussed.The total dose experiment results show that the breakdown voltage and the on-state resistance barely change with the accumulated dose.However,the relationships between the threshold voltages of the samples and the accumulated dose are more complex,and not only positively drift,but also negatively drift.At the end of the total dose experiment,we select the group of samples which have the smaller threshold voltage shift to carry out the single event effect studies.We find that the samples with appropriate thickness ratio SiO2-Si3N4 films have a good radiation-hardening ability.This method may be useful in solving both the SEGR and the total dose problems with the composite SiO2-Si3N4 films. 展开更多
关键词 power VDMOS device total dose effects single event effects composite SiO2-Si3N4 films
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Effect of boron doping on waterproof and dielectric properties of polyborosiloxane coating on SiO2f/SiO2 composites 认领 引用 被引量:8
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作者 Long XIA Siru LU +7 位作者 Bo ZHONG Longnan HUANG Hua YANG Tao ZHANG Haibo HAN Pan WANG Li XIONG Guangwu WEN 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2019年第8期2017-2027,共11页
A hydrophobic coating of the silica fiber reinforced silica composites(SiO2f/SiO2) was synthesized by sol-gel method using methyltriethoxy-silane(MTES) and boric acid(B(OH)3) as raw materials. The relationship among b... A hydrophobic coating of the silica fiber reinforced silica composites(SiO2f/SiO2) was synthesized by sol-gel method using methyltriethoxy-silane(MTES) and boric acid(B(OH)3) as raw materials. The relationship among boron doping, chemical structure of precursors and durability of hydrophobic coatings was discussed. The Si-O-B and methyl groups were successfully introduced in the gel precursors according to the FT-IR and XPS results. The resins were filled in the internal and surface holes of the SiO2f/SiO2 composites partially or completely, which is beneficial to reduce the physical adsorption of the moisture. In addition, hydroxyl groups of the SiO2f/SiO2 composites reacted with the resins and hydrophobic methyl groups were introduced, leading to the reduction of the chemical adsorption of water. Also, the boron doping was beneficial to enhancing the physical cross-linking between the coating and the SiO2f/SiO2 composites, and improved the adhesion of the coating to the substrate. The results show that the optimal hydrophobic coating with contact angle 130.33°, moisture absorption 0.33% and adhesion level 1 is obtained when the molar ratio of MTES to B(OH)3 is 10:4. The real permittivity of M10B4 is constant in the range of 2.32–2.51 and the dielectric tangent loss is constant in the range of 5.5 × 10-4–8.7 × 10-3. The hydrophobic coating has excellent dielectric properties. 展开更多
关键词 Adhesion Dielectric Hydrophobic Polyborosiloxane SiO2f/SiO2 composites
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Grain Size and Wettability of TiO_2/SiO_2 Photocatalytic Composite Thin Filing 认领 引用 被引量:11
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作者 Jiaguo Yu, Xiujian Zhao, Jimmy C Yu, Jun Lin (State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China Deportment of Chemised The Chinese University of Hong Kong, Hong Kong, 《Rare Metals》 SCIE EI CAS 2001年第2期81-86,共6页
The uniform transparent TiO2/SiO2 photocatalytic composite thin films are prepared by sol-gel method on the soda lime glass substrates, and characterized by UV-visible spectroscopy, X-ray diffraction (XRD), transmissi... The uniform transparent TiO2/SiO2 photocatalytic composite thin films are prepared by sol-gel method on the soda lime glass substrates, and characterized by UV-visible spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), BET surface area, FTIR spectroscopy and X-ray photoelectron spectroscopy (XPS). It was found that the addition of SiO2 to TiO2 thin films can suppress the grain growth of TiO2 crystal, increase the hydroxyl content on the surface of TiO2 films, lower the contact angle for water on TiO, films and enhance the hydrophilic property of TiO2 films. The super-hydrophilic TiO2/SiO2 photocatalytic composite thin films with the contact angle of 0((o) under bar) are obtained by the addition of 10%-20% SiO2 in mole fraction. 展开更多
关键词 sol-gel method TiO2/SiO2 photocatalytic composite thin films grain size wettability
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Preparation and Characterization of Tetracomponent ZnO/SiO2/SnO2/TiO2Composite Nanofibers by Electrospinning 认领 引用
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作者 Chao Song Xiangting Dong 《Advances in Chemical Engineering and Science》 CAS 2012年第1期108-112,共5页
[Zn(CH3COO)2 + PVP]/[C2H5O)4Si + PVP]/[SnCl4 + PVP]/[Ti(OC4H9)4 + CH3COOH + PVP] precursor composite fibers have been fabricated through self-made electrospinning equipment via electrospinning tech-nique. ZnO/SiO2/SnO... [Zn(CH3COO)2 + PVP]/[C2H5O)4Si + PVP]/[SnCl4 + PVP]/[Ti(OC4H9)4 + CH3COOH + PVP] precursor composite fibers have been fabricated through self-made electrospinning equipment via electrospinning tech-nique. ZnO/SiO2/SnO2/TiO2 composite nanofibers were obtained by calcination of the relevant precursor composite fibers. The samples were characterized by thermogravimetric-differential thermal analysis (TG-DTA), X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR), and Scanning electron microscopy (SEM). TG-DTA analysis reveals that solvents, organic compounds and inorganic in the precursor composite fibers are decomposed and volatilized totally, and the mass of the samples kept constant when sintering temperature was above 900?C, and the total mass loss percentage is 88%. XRD results show that the precursor composite fibers are amorphous in structure, and pure phase ZnO/SiO2/SnO2/TiO2 com-posite nanofibers are obtained by calcination of the relevant precursor composite fibers. FTIR analysis manifests that pure inorganic oxides are formed. SEM analysis indicates that the width of the precursor composite fibers is ca. 1.485 ± 0.043 μm. The width of the ZnO/SiO2/SnO2/TiO2 composite nanofibers is ca. 1145.098 ± 68.093 nm. 展开更多
关键词 ZnO/SiO2/SnO2/TiO2 Tetracomponent Composite Nanofibers Electrospinning
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Si/Ti原子比对TiO_2-SiO_2复合薄膜亲水性能与摩擦磨损性能的影响 认领 引用
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作者 王晓宏 赵青南 +3 位作者 常潇 陆文涛 董玉红 赵杰 《人工晶体学报》 CAS 北大核心 2019年第4期579-586,共8页
采用直流(DC)反应磁控溅射法在玻璃上制备了不同Si/Ti原子比的TiO_2-SiO_2复合薄膜。使用X射线衍射仪(XRD)、场发射扫描电子显微镜(SEM)、X射线光电子能谱仪(XPS)、紫外可见分光光度计、CA-XP150型接触角仪、UMT-2型多功能微摩擦仪,研... 采用直流(DC)反应磁控溅射法在玻璃上制备了不同Si/Ti原子比的TiO_2-SiO_2复合薄膜。使用X射线衍射仪(XRD)、场发射扫描电子显微镜(SEM)、X射线光电子能谱仪(XPS)、紫外可见分光光度计、CA-XP150型接触角仪、UMT-2型多功能微摩擦仪,研究了不同Si/Ti原子比的TiO_2-SiO_2复合薄膜微观结构、表面形貌、亲水性能和摩擦磨损性能。结果表明,所制备的纯TiO_2薄膜具有锐钛矿结构,其平均晶粒尺寸为11 nm,TiO_2-SiO_2复合薄膜呈现非晶结构,其粒子尺寸相对减小;随着Si/Ti原子比的增大,薄膜在可见光区的平均透过率从76. 6%增加到84. 3%。当复合薄膜中Si/Ti原子比为1∶2时,薄膜的摩擦系数为0. 11,薄膜具有最佳的亲水性能;在紫外光照射2 h后水接触角降到3. 0°;在黑暗中放置30 h后水接触角略增加到7. 7°。 展开更多
关键词 TiO2-SiO2复合薄膜 Si/Ti比 亲水性能 摩擦性能 直流磁控溅射
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A flexible CNT@nickel silicate composite film for high-performance sodium storage 认领 引用 被引量:3
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作者 Ziyue Zhou Wenping Si +5 位作者 Pengyi Lu Wenlei Guo Lei Wang Tao Zhang Feng Hou Ji Liang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第8期29-37,I0002,共9页
Due to the sufficient ion diffusion channels provided by the large interlayer spacing, layered silicates are widely considered as potential anode materials for lithium ion and sodium ion batteries. However, due to the... Due to the sufficient ion diffusion channels provided by the large interlayer spacing, layered silicates are widely considered as potential anode materials for lithium ion and sodium ion batteries. However, due to the poor electronic conductivity, the application of layered silicates for electrochemical energy storage has been greatly limited. Carbon nanotube(CNT) film has excellent electrical conductivity and a unique interconnected network, making it an ideal matrix for composite electrochemical material. We herein report a CNT@nickel silicate composite film(CNT@NiSiO) fabricated by a SiO2-mediated hydrothermal conversion process, for sodium storage with excellent electrochemical properties. The obtained composite possesses a cladding structure with homogeneous nanosheets as the outermost and CNT film as the inner network matrix, providing abundant ion diffusion channels, high electronic conductivity, and good mechanical flexibility. Due to these merits, this material possesses an excellent electrochemical performance for sodium storage, including a high specific capacity up to 390 mAh g-1 at 50 mA g-1, good rate performance up to 205 mAh g-1 at 500 mA g-1, and excellent cycling stability. On this basis, this work would bring a promising material for various energy storage devices and other emerging applications. 展开更多
关键词 Sodium ion storage Nickel silicate Carbon nanotubes Composite film SiO2-mediated hydrothermal conversion
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减反射可见光与反射近红外线双功能镀膜玻璃 认领 引用 被引量:7
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作者 赵青南 董玉红 +2 位作者 赵杰 曾妩 卢秀强 《材料科学与工程学报》 CAS CSCD 北大核心 2012年第1期5-8,共4页
采用溶胶-凝胶工艺,用提拉法在光伏玻璃上制备了玻璃/TiO2-SiO2/SnO2∶F/SiO2减反射可见光与反射近红外双功能膜。用拟合方法研究了TiO2掺量对TiO2-SiO2膜层折射率的影响、以及溶胶中水含量对SiO2膜层折射率的影响;研究了快速热处理温度... 采用溶胶-凝胶工艺,用提拉法在光伏玻璃上制备了玻璃/TiO2-SiO2/SnO2∶F/SiO2减反射可见光与反射近红外双功能膜。用拟合方法研究了TiO2掺量对TiO2-SiO2膜层折射率的影响、以及溶胶中水含量对SiO2膜层折射率的影响;研究了快速热处理温度对SnO2∶F膜结构和方块电阻的影响,用紫外-可见光谱(UV-Vis)测试了膜层的透射率,用扫描电镜(SEM)观察了膜层的表面形貌。结果表明,TiO2掺量可以使TiO2-SiO2膜层的折射率在1.49~1.97之间变化,SiO2溶胶中的水含量能够在膜面上形成微孔,降低SiO2膜层的折射率。通过优化工艺,制备出了在可见光范围平均透过率约为96%、1120nm波长近红外起始反射的双功能复合膜。对得到的结果进行了讨论。 展开更多
关键词 SiO2/SnO2:F/SiO2复合膜 溶胶-凝胶 可见光减反射 近红外反射
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