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Biphasic interface engineering:A machine learning-guided strategy for optimizing selective oxidative desulfurization of FCC slurry oil 认领 引用
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作者 Xiaoxiao Xing Peiwen Wu +7 位作者 Yiru Zou Zhaozeng Gao Zhendong Yu Minmeng Tang Yanhong Chao Wenshuai Zhu Zhichang Liu Chunming Xu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2026年第5期375-389,共15页
The non-destructive desulfurization of aromatic structures is crucial for the high-value utilization of FCC slurry oil.Hydrodesulfurization causes aromatic saturation,impairing the suitability of slurry oil as needle ... The non-destructive desulfurization of aromatic structures is crucial for the high-value utilization of FCC slurry oil.Hydrodesulfurization causes aromatic saturation,impairing the suitability of slurry oil as needle coke feedstock.Therefore,developing methods capable of selective desulfurization while preserving aromatics is essential.Herein,we address the critical challenges impeding the application of oxidative desulfurization(ODS)to slurry oil,specifically its complex composition,high sulfur content,prohibitively high viscosity,and inefficient oil-water interfacial mass transfer.An innovative ODS strategy based on biphasic interface regulation was proposed.By constructing a catalytic system through the combination of polyoxometalate and organic cationic modifiers to stabilize the oil-water interface,enhanced mass transfer efficiency was achieved.These catalysts function as surfactant-like homogeneous catalysts during H2O2 mediated oxidation,while enabling rapid separation after reaction.Systematic model system studies identified catalysts with exceptional sulfur-oxidation selectivity,operating via dynamic peroxo-species formation from terminal oxygen of W=O activation by superoxide radicals.Deployment in real slurry oil under Bayesian-optimized conditions reduced sulfur content from 1.60 wt%to 0.34 wt%while completely preserving the core feedstock components 3-4 ring aromatic components and maintaining 86.4%slurry recovery.This research provides a technologically innovative and practically viable pathway for desulfurization of slurry oils with remaining high aromatic contents. 展开更多
关键词 FCC slurry oil Oxidative desulfurization Interface catalysis Needle coke Machine learning
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Multi-scale coherent interfaces in core-shell Sr0.875La0.1TiO3-based textured ceramics for enhanced high temperature thermoelectric performance 认领 引用 被引量：1
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作者 Zhihao Lou Ziyao Wei +4 位作者 Xiaoyu Xu Ping Zhang Jingji Zhang Jie Xu Feng Gao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2026年第5期279-289,I0007,共11页
SrTiO3-based thermoelectric ceramics show potential for high-temperature energy harvesting but face challenges from inefficient carrier transport and high thermal conductivity.This work presents a multi-scale struc... SrTiO3-based thermoelectric ceramics show potential for high-temperature energy harvesting but face challenges from inefficient carrier transport and high thermal conductivity.This work presents a multi-scale structural engineering strategy to address these challenges,fabricating textured Sr0.875La0.1Ti O3m Ti/10 wt%Bi2O3(SLTTB)ceramics via plate-like SrTiO3templates.Through this design,the ceramics form a unique core-shell architecture,where template seeds act as growth cores for epitaxially alignedoriented grains,forming coherent interfaces with a precipitate-rich interlayer and a precipitate-free shell.In the interlayer,uniformly distributed“peanut-shaped”Bi-Ti_nO2n-1nanoparticle pairs enhance electron mobility and phonon scattering.The hierarchical microstructure creates multiscale coherent interfaces that reduce electron grain boundary scattering,enabling preferential electron transport pathways parallel to the casting direction.This architecture enables the decoupling of electrical and thermal properties,with a power factor reaching 1815μW/m/K2at 1073 K with thermal conductivity suppressed by interfacial and nanoparticle scattering.Consequently,the SLTTB textured ceramic achieves a notable ZT of 0.64 at 1073 K,a significant enhancement over conventional counterparts.This work demonstrates a multi-scale structural strategy integrating template-induced texture,core-shell design,and nanoscale interface modulation to decouple the electrical and thermal properties of SrTiO3-based materials,and provides a roadmap for tailoring the electrical-thermal transport properties of thermoelectric textured ceramics. 展开更多
关键词 Strontium titanate Thermoelectrics Textured ceramics Core-shell architecture Coherent interfaces
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Stability of base-exposed backfill roof considering interfaces between adjacent drifts in underhand drift-and-fill mining 认领 引用 被引量：1
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作者 Qinghai Ma Guangsheng Liu +2 位作者 Xiaocong Yang Lijie Guo Andy Fourie 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2026年第1期214-229,共16页
Stability of base-exposed backfill roof in underhand drift-and-fill mining is crucial for the safety of those working beneath.Given the commonly used primary-and-secondary mining sequence,interfaces are formed between... Stability of base-exposed backfill roof in underhand drift-and-fill mining is crucial for the safety of those working beneath.Given the commonly used primary-and-secondary mining sequence,interfaces are formed between adjacent filled drifts,which can weaken the integrity of the backfill roof.These interfaces also lead to two common drift layouts:aligned drifts and staggered drifts.However,less attention has been paid to the interfaces and the two drift layouts were not adequately distinguished in previous studies.In this paper,the interfaces between filled drifts were firstly considered to investigate the stability of backfill roof.Failure modes and strength requirements of backfill roof in aligned and staggered drifts are comprehensively investigated by FLAC3D,with a focus on considerations of varied shear parameters of the interfaces.Results show that failure modes in aligned drifts transition from block sliding to top caving,bottom caving or sloughing as the interface cohesion increases from zero to at least half of the backfill cohesion.Further increases in interface cohesion allow aligned drifts to behave as if there are no interfaces between them.The critical stability conditions of backfill roof in aligned drifts were mostly determined by the interface strength instead of the backfill strength.However,the stability of backfill roof in staggered drifts is barely affected by the interface strength.The outcomes are expected to provide references for mining engineers to optimize drift layouts and perform cost-effective backfill roof strength design at mines using underhand drift-and-fill mining method. 展开更多
关键词 Base-exposed backfill Interface Failure mode Strength requirement Underhand drift-and-fill mining
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Direct versus indirect 2D/3D heterojunction engineering:Ordered interface design for ultastable perovskite solar cells 认领 引用 被引量：1
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作者 Kaiyu Wang Xiuhong Sun +7 位作者 Cheng Peng Qiangqiang Zhao Bingqian Zhang Tianci Wu Xiaoxu Zhang Shenglai Wang Xiao Wang Shuping Pang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2026年第3期520-527,共8页
While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor ... While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor often overlooked.Disordered interfaces exhibit thermodynamic metastability,where ion diffusion induces sequential phase transitions from low-n to high-n phases.Here,we construct atomically ordered 2D/3D interfaces using phase-pure 2D perovskite capping layers,which reduce the interfacial phase transition rate by 95%and effectively suppress ion migration.As a result,devices exhibit outstanding operational stability,retaining over 99%of their initial power conversion efficiency after 1500 h of continuous operation,along with excellent thermal durability at 85℃.These findings identify interfacial order as a critical parameter for regulating ion dynamics and phase behavior,providing a robust design principle for achieving high-efficiency,long-lifetime perovskite technologies. 展开更多
关键词 2D/3D heterostructures Ordered interface Operational stability
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In situ polymerized fire extinguishing crosslinked quasi-solid-state electrolytes enabling stable interfaces in sodium metal batteries 认领 引用
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作者 Xiaoqian Su Yanan Hou +3 位作者 Saihua Jiang Fei Xie Kaiang Su Congling Shi 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2025年第12期109-118,I0005,共10页
Sodium metal batteries(SMBs)represent a promising alternative for large-scale energy storage and lowspeed electric vehicles,with resource-sustainable and cost-effective characteristics.However,its practical applicatio... Sodium metal batteries(SMBs)represent a promising alternative for large-scale energy storage and lowspeed electric vehicles,with resource-sustainable and cost-effective characteristics.However,its practical application is hindered by the high reactivity of sodium metal,interfacial and structural instability,and fire safety risks.Herein,a poly(1,3-dioxolane)(PDOL)crosslinked quasi-solid-state electrolyte(TPQSE)with fire extinguishing property and superior interface compatibility with sodium(Na)anodes and Na3V2(PO4)3(NVP)cathodes is prepared via in situ polymerization at room temperature(RT),utilizing trimethylolpropane triglycidyl ether(TTE)as a crosslinker in coordination with ethoxy(pentafluoro)cyclotriphosphazene(PFPN).The crosslinked network of TPQSE and the distinct solvation properties of TPDOL and PFPN facilitate Na-ion desolvation while enhancing antioxidant stability of TPQSE.Moreover,multifunctional PFPN improves fire safety through condensed-phase dense char layer formation and gas-phase free radical capturing.It also constructs uniform,dense,and inorganic-rich interphases between electrodes and electrolytes,strengthening interfacial stability.Consequently,the prepared electrolyte exhibits high ionic conductivity(2.109 mS cm-1at RT),high Na+transference number(0.570),and extended electrochemical window to 4.805 V.The Na‖TPQSE‖Na symmetric cell presents impressive cycling stability over 4510 h,and the Na‖TPQSE‖NVP cell displays outstanding rate capability and stable long-term cycling(≥2300 cycles).This work provides a promising approach for developing safe and high-performance quasi-solid-state sodium metal batteries. 展开更多
关键词 In situ polymerized Poly(1 3-dioxolane) Electrode-electrolyte interface Fire extinguishing Sodium metal batteries
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Interface behavior of steel-slag-air during tundish filling process:physical modeling and mathematical simulation 认领 引用
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作者 Yu-Hang Wang Hai-Yan Tang +3 位作者 Kai-Min Wang Zhen-Dong Wang Xing-Yu Jia Jia-Quan Zhang 《Journal of Iron and Steel Research International》 SCIE EI CSCD 2026年第3期266-282,共17页
In view of the frequent deterioration of molten steel quality during the tundish filling process,the slag-steel-air interface behavior in a tundish,including liquid level fluctuation,slag eyes,slag entrapment and air ... In view of the frequent deterioration of molten steel quality during the tundish filling process,the slag-steel-air interface behavior in a tundish,including liquid level fluctuation,slag eyes,slag entrapment and air suction during the steady-state casting and filling process,was comparatively studied through physical modeling and mathematical simulation methods.During the filling process,the liquid surface forms a large-size slag eye under the impact of molten steel from a ladle shroud,which simultaneously results in a violent fluctuation of liquid level.Concurrently,the liquid flow entrains the air phase and the cover slag into the tundish impact zone,resulting in slag entrapment and air suction.At filling flow rates of 1.5Q,2.0Q,and 2.5Q(Q is the flow rate under steady-state casting),the amount of slag entrapped is 8.39×10-5,9.65×10-5,and 12.7×10-5m3,respectively,while the volume of air aspirated is 0.84×10-4,1.47×10-4,and 2.01×10-4m3,indicating that slag entrapment and air suction intensify with an increase in tundish filling flow rate.Flow field characterization identifies eddy currents in the impact zone as the primary driver of the above phenomena.Proper filling process parameters were proposed to improve the steel quality during the tundish filling. 展开更多
关键词 Mathematical simulation Physical modeling Tundish filling process Interface behavior Steel-slag-air interface
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EM-DETR:GUI组件实时检测网络 认领 引用
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作者 严武军 王程 +1 位作者 张晓丽 景莹 《计算机技术与发展》 2026年第2期118-125,共8页
在艺术与科技研究领域中,针对目前大部分现有公开数据集过于老旧而导致已有研究方法在实际GUI(Graphical User Interface)检测中因界面所特有的组件种类多样、背景复杂的情况,同时因高分辨率显示器使得部分组件更小更密集从而导致检测... 在艺术与科技研究领域中,针对目前大部分现有公开数据集过于老旧而导致已有研究方法在实际GUI(Graphical User Interface)检测中因界面所特有的组件种类多样、背景复杂的情况,同时因高分辨率显示器使得部分组件更小更密集从而导致检测效率不高和检测精度瓶颈等问题,该文依托太原师范学院智能科技与艺术创新科研平台自行构建GUI数据集并基于RT-DETR模型进行改进提出EM-DETR,构建面向GUI组件检测任务的实时目标检测网络创新性优化策略。为突破低质量样本与计算效率的双重限制,创新构建了引入增强定位敏感区域的表达能力模块的EMViT轻量化骨干网络;与此同时,为改善最近邻插值法可能出现细节丢失、锯齿状边缘和图像失真等问题,引入DySample上采样算子;最后为了解决低质量样本回归难题,设计基于WIoUv3的动态梯度分配策略。本实验在太原师范学院智能科技与艺术创新科研平台提供的GUI数据集中验证了检测精度及效率平衡方面的有效性。实验结果表明,检测平均精度(mAP)达到了89.8%,相较于原始RT-DETR提升了9.53百分点,同时,EM-DETR在检测速度上也表现出色,在GUI组件检测这一细分场景下,首次将RT-DETR架构的精度提高到可落地水平,在保持可接受的实时性同时大大提高了检测正确率。现已将其应用到教育部产学合作协同育人公示企业山西赛迩教育科技有限公司中的产品研发环节,取得良好效果。 展开更多
关键词 RT-DETR GUI组件检测 EMViT EfficientViT_M0 MLLA模块 DySample WIoUv3损失函数
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Brain-computer interfaces re-shape functional neurosurgery 认领 引用
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作者 Thomas Kinfe Steffen Brenner Nima Etminan 《Neural Regeneration Research》 SCIE CAS CSCD 2026年第3期1122-1123,共2页
Invasive as well as non-invasive neurotechnologies conceptualized to interface the central and peripheral nervous system have been probed for the past decades,which refer to electroencephalography,electrocorticography... Invasive as well as non-invasive neurotechnologies conceptualized to interface the central and peripheral nervous system have been probed for the past decades,which refer to electroencephalography,electrocorticography and microelectrode arrays.The challenges of these mentioned approaches are characterized by the bandwidth of the spatiotemporal resolution,which in turn is essential for large-area neuron recordings(Abiri et al.,2019). 展开更多
关键词 microelectrode arraysthe brain computer interfaces electroencephalography electrocorticography interface central peripheral nervous system non invasive neurotechnologies functional neurosurgery microelectrode arrays
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Adhesion Reinforcement of Electrode-Electrolyte Interface in Flexible Electrochemical Energy Storage Devices 认领 引用
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作者 Xian Xie Qiuhong Wang +3 位作者 Faheem Mushtaq Kelong Ao Hong Zhao Walid A.Daoud 《Nano-Micro Letters》 SCIE EI CAS CSCD 2026年第7期842-872,共31页
Wearable and deformable electronics are becoming increasingly essential components of modern healthcare and daily life.To power such devices,flexible electrochemical energy storage(FEES)plays a critical role.The pract... Wearable and deformable electronics are becoming increasingly essential components of modern healthcare and daily life.To power such devices,flexible electrochemical energy storage(FEES)plays a critical role.The practical performance of FEES is dominated by charge and mass transfer at the electrodeelectrolyte interface,similar to many rigid battery technologies.However,a unique challenge for FEES is the durability of this interface under deformation.Herein,we present the first comprehensive review of the interface physics,unveiling the crucial role of interface adhesion in the mechanical endurance of FEES.By bridging adhesion physics,material chemistry,and device mechanics,adhesion reinforcement strategies are comprehensively discussed and quantitatively compared,providing multi-scale mechanisms for optimizing FFES interface-from nanoscale bond engineering to microscale surface topology,mechanical interlocking,and macroscale device design.Further,inspired by the synergetic effect of adhesion mechanisms,we propose potential research directions for durable electrode-electrolyte interfaces under dynamic deformation.We also revisit the evaluation of flexibility and electrochemical performance,proposing an application-driven bending index for device assessment.These insights on electrode-electrolyte interface physics of FEES will facilitate the flourishing future of flexible devices. 展开更多
关键词 Flexible batteries Wearable electronics Adhesion Interface Deformability
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Synergistic enhancement of strength and ductility of Ti2AlC/TiAl through Mn solid solution and interface manipulation 认领 引用
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作者 Yuanzheng Wei Yilu Li +3 位作者 Shili Shu Hongyu Yang Feng Qiu Qichuan Jiang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2026年第2期610-622,共13页
Introducing Ti2AlC particles into TiAl alloys can effectively improve their strength,but this can also lead to stress concentration at the interface,resulting in the reduction of ductility.Therefore,Mn is adopted t... Introducing Ti2AlC particles into TiAl alloys can effectively improve their strength,but this can also lead to stress concentration at the interface,resulting in the reduction of ductility.Therefore,Mn is adopted to synergistically improve the strength and ductility of the Ti2AlC/TiAl composite through solid solution and interface manipulation.The first-principles calculation shows the Ti-Mn bonds are formed at the Ti2AlC/TiAl interface after Mn doping,characterized primarily by metallic bonds with some covalent bonding.This combination preserves strength while enhancing ductility.Then,Ti2AlC/TiAl-Mn composite is prepared.The Ti2AlC,with an average size of 1.6μm,is uniformly distributed within the TiAl matrix.Mn doping reduces the lamellar colony size and lamellar thickness by 25.1%and 27.4%,respectively.A small quantity of Mn accumulates at the boundaries of the lamellar colonies.The Mn content must be controlled to avoid segregation,which may negatively impact performance.The yield stress,ultimate compressive stress,fracture strain,and product of strength and plasticity of the Ti2AlC/TiAl-Mn composite have been increased by 5.5%,11.5%,10.4%,and 23.0%,respectively,compared to those of the Ti2AlC/TiAl composite.The enhancement in strength is due to the combined effects of grain refinement,solid solution of Mn,and twining strengthening.Grain refinement and twin strengthening also can reduce stress concentration and improve ductility.In addition,at the electronic level,the Ti-Mn bond formed at the interface is contributed to the improvement of ductility. 展开更多
关键词 titanium aluminum alloy composites microstructure interfaces mechanical properties
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Interface-Engineered Strategy on Carbon Nanotubes to Chemical Stabilize Graphene as a Self-Healing Fiber Electrode for Superior Capacitive Deionization 认领 引用
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作者 Rui Wang Ruilin Wu +2 位作者 Biao Fang Han Liang Runwei Mo 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2026年第2期450-459,共10页
Nanocomposite technology is an effective strategy to enhance the performance of capacitive deionization(CDI).However,the poor interfacial interactions between the nanofillers and matrices limit their further optimizat... Nanocomposite technology is an effective strategy to enhance the performance of capacitive deionization(CDI).However,the poor interfacial interactions between the nanofillers and matrices limit their further optimization and commercial application.Here,we developed an interface engineering strategy to prepare a high-strength and high-toughness fiber electrode based on holey reduced graphene oxide(HRGO)and carboxylated carbon nanotubes(CCNT)through introducing borate bonds as bridging interactions.The interface interaction between HRGO and CCNT is significantly enhanced by the formation of dynamic cross-linked borate bonds,which not only effectively preventπ-πstacking and construct hierarchical ion transport channels to enhance ion transport efficiency and reaction kinetics,but also significantly improve mechanical stability and long-cycle performance based on self-healing properties in the fiber electrode.This configuration showed remarkably enhanced desalination capacity(30.6 mg g-1)and higher desalination rate(6.12 mg g-1 min-1),with cycling performance exceeding 90%,which exceeds previously reported values.Density functional theory calculations further reveal the mechanism by which the nanocomposite interface affects the CDI performance.Based on this excellent performance,we established a recirculating desalination hydrogen production system consisting of multiple CDI units connected in series with a hydrogen production unit.This effective strategy opens a new way to optimize the nanocomposite interfaces and achieve efficient electrochemical reactions. 展开更多
关键词 capacitive deionization macroscopic assemblies mechanical stability nanocomposite interfaces self-healing
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Stable interfaces in lithium metal batteries constructed via in-situ electrolyte reformulation 认领 引用
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作者 Kuan DAI Feng-jing WU +3 位作者 Mu-lan QIN Chang-wei SU Wan-min LIU Xin-ye LUO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2026年第4期1281-1293,共13页
Li2CO3 was introduced into LiPF6-based electrolytes and the electrolytes were stored at 40°C.Nuclear magnetic analysis of electrolytes and X-ray diffraction characterization of reaction residues demonstr... Li2CO3 was introduced into LiPF6-based electrolytes and the electrolytes were stored at 40°C.Nuclear magnetic analysis of electrolytes and X-ray diffraction characterization of reaction residues demonstrate the formation of LiPO2F2 and LiF during storage.This reformulated electrolyte boosts lifespan and Coulombic efficiency(CE)in Li||Li and Li||Cu cells,with Li||Li cells stably cycling for>800 h and 300 h at 0.5 mA/cm2 and 1.0 mA/cm2,respectively.Moreover,with the optimal content of Li2CO3,the CE of the reformulated electrolyte(91.56%)is greatly improved compared to that of the standard electrolyte(81.99%).The compatibility and enhanced rate performance of the reformulated electrolyte are also exhibited in Li||NCM full cells with a moderately high mass loading of 9.6 mg/cm2. 展开更多
关键词 lithium carbonate lithium metal battery interface electrolyte lithium dendrites
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Tailoring the ultra-fine size and thermal stability of Au(Cu)nanoparticles by application of interface thermodynamics 认领 引用
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作者 Panmei Liu Shuo Ma +2 位作者 Yuan Huang Yongchang Liu Zumin Wang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2026年第1期279-289,共11页
Ultra-fine sizes and high thermal stability are often mutually exclusive for nanocrystalline(NC)materials because the high grain boundary(GB)energy of nanograins provides a large driving force for grain coarsening.All... Ultra-fine sizes and high thermal stability are often mutually exclusive for nanocrystalline(NC)materials because the high grain boundary(GB)energy of nanograins provides a large driving force for grain coarsening.Alloying is a classical strategy for stabilizing the microstructure of NC materials.However,the stabilization effects of alloying on NC materials typically rely on the segregation of solute atoms at GBs,which imposes restrictions on the selection of possible alloy systems.In this study,it is revealed experimentally and corroborated theoretically that the interface energies can be continuously regulated by simply manipulating the alloy composition in simple solid-solution alloy systems,enabling the control of the ultra-fine sizes and thermal stability of the alloys without GB segregation.In a model system of NC Au(Cu)-SiO2films,the dissolved Cu in Au can be used as a very accurate tool to tailor the interface energies of NC Au(Cu)-SiO2film,leading to ultra-fine(below 2 nm)Au(Cu)nanoparticles with exceptional thermal stability.Such Cu-induced grain refinement and thermal stabilization effects are supported by interface thermodynamic calculations.This study thus provides an alloying stabilization strategy without GB segregation,which broadens the scope for developing thermally stable NC alloy systems. 展开更多
关键词 Nanocrystalline materials Interface energy Grain growth Thermal stability
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Phase composition of slag-iron interface and elemental distribution behavior between hot metal and Ti-bearing electric furnace slags 认领 引用
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作者 Jian-fa JING Yu-feng GUO +3 位作者 Shuai WANG Feng CHEN Ling-zhi YANG Guan-zhou QIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2026年第4期1320-1334,共15页
The phase composition at the slag-iron interface and the distribution behavior of titanium,vanadium,chromium and silicon between hot metal and Ti-bearing electric furnace slag were thoroughly explored.The basicity ran... The phase composition at the slag-iron interface and the distribution behavior of titanium,vanadium,chromium and silicon between hot metal and Ti-bearing electric furnace slag were thoroughly explored.The basicity range for the anosovite phase region was defined by using a phase diagram and a minimum smelting temperature was set at 1540℃.Thermodynamic calculations demonstrate that the activities of TiO2 and SiO2 in the slag decrease with increasing basicity,while those of V2O3 and Cr2O3 increase.Similarly,the activities of[Ti]and[Si]in the molten metal decrease,while those of[V]and[Cr]rise with increasing basicity.As basicity increases,the distribution ratios,LTi and LSi decrease,whereas LV and LCr increase.Significantly,the recovery efficiencies of vanadium and titanium are improved with higher basicity.The primary phases identified in the slag include anosovite,diopside,and titanium spinel.However,when the basicity exceeds 0.8,the formation of the perovskite phase becomes less favorable,suggesting that basicity should be maintained at or below 0.8. 展开更多
关键词 slag-iron interface elemental distribution coefficients smelting temperature anosovite activity
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Eliminating Schottky Barrier via interface state manipulation on phase-tailored 2D/3D perovskite solar cells 认领 引用
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作者 Junmin Xia Hao Gu +15 位作者 Ziyi Wang Mengting Chen Hui Hong Zhifeng Li Bo Cai Kun Cao Jia Guo Guangbao Wu Ke Guo Shengwen Li Annan Zhu Shi Chen Yongqing Cai Chao Liang Shufen Chen Guichuan Xing 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2026年第1期760-769,I0017,共10页
Surface passivation via two-dimensional(2D)perovskite has emerged as a promising strategy to enhance the performance of perovskite solar cells(PSCs)due to the effective compensation of interfacial states.However,the i... Surface passivation via two-dimensional(2D)perovskite has emerged as a promising strategy to enhance the performance of perovskite solar cells(PSCs)due to the effective compensation of interfacial states.However,the in situ grown 2D perovskite passivation layers typically comprise a mixture of multiple dimensionalities at the interface,where band alignment has only been portrayed qualitatively and empirically.Herein,the interface states for precisely phase-tailored 2D perovskite passivated PSCs are quantitatively investigated.In comparison to traditional passivation molecules,2D perovskite layers based on 4-trifluoromethyl-phenylethylammonium iodide(CF3PEAI)exhibit an increased work function,introducing desirable downward band bending to eliminate the Schottky Barrier.Furthermore,precisely phase-tailored 2D layers could modulate the interface trap density and energetics.The n=1 film delivers optimal performance with a hole extraction efficiency of 95.1%.The optimized n-i-p PSCs in the two-step method significantly improve PCE to 25.40%,along with enhanced photostability and negligible hysteresis.It highlights that tailoring in the composition and phase distribution of the 2D perovskite layer could modulate the interface states at the 2D/3D interface. 展开更多
关键词 Perovskite solar cells Interface states Band alignment Phase tailoring
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Rock-concrete composite specimens with different interface inclination angles:Creep characteristics and nonlinear damage constitutive model 认领 引用
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作者 YAO Wei-jing NOUBISSI KENGNE Honorine +2 位作者 LIU Yu PANG Jian-yong XU Han-bing 《Journal of Central South University》 SCIE EI CAS CSCD 2026年第2期968-986,共19页
Weak rock-concrete interfaces significantly affect the stability of underground supporting structures.This study aims to investigate the effects of interface inclination on the creep behavior and failure mechanisms of... Weak rock-concrete interfaces significantly affect the stability of underground supporting structures.This study aims to investigate the effects of interface inclination on the creep behavior and failure mechanisms of composite specimens.Seven rock-concrete composite specimens with different inclination angles under hydrothermal curing at 60℃were prepared,and uniaxial and graded loading creep tests were completed.The results show that with increasing interface inclination,the compressive strength of the composite specimens initially decreases and then increases,with the minimum strength observed at inclinations between 60°and 75°.Three typical failure patterns were identified:axial failure,composite failure,and interface failure.The creep failure strength exceeded the uniaxial compressive strength,indicating improved time-dependent deformation resistance under elevated temperature curing.The instantaneous strain initially decreases and then increases as the interface inclination angle grows.Compared to 0°inclination,specimens with 45°,60°,75°,and 90°inclinations exhibited reductions in instantaneous strain of 2.64%,18.84%,23.29%,and 0.73%,respectively.The steady-state creep rate and creep ratio exhibited a decrease-stabilization-increase trend with increasing stress levels.Creep strain increased with increasing stress levels for all inclinations,with a sharp increase near the failure stage.A nonlinear constitutive model considering interface inclination and creep damage was developed based on damage theory.A nonlinear damage-based constitutive model incorporating interface inclination effects was developed,and its theoretical predictions closely matched the experimental data in all creep stages.These findings provide a quantitative understanding of creep failure mechanisms in rock-concrete interfaces and provide practical references for enhancing the safety of underground support systems. 展开更多
关键词 rock-concrete composite interface inclination stress level creep nonlinear damage model
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A prediction model for axial installation force of interference-fit bolt in CFRP bolted joint and its deformation mechanism of contact interface at bolt-hole under static loading 认领 引用
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作者 Duquan ZUO Jie LIU +4 位作者 Yuejie CAO Minghao ZHANG Shaoqing JIN Yaoming FU Zengqiang CAO 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2026年第3期631-642,共12页
This paper investigates the “brush-like”deformation phenomenon of the contact interface at the bolt-hole during the interference-fit installation of high-locking bolts under static loading in CFRP connection structu... This paper investigates the “brush-like”deformation phenomenon of the contact interface at the bolt-hole during the interference-fit installation of high-locking bolts under static loading in CFRP connection structures.An innovative theoretical model is proposed to predict axial installation force,specifically designed for moderate interference-fit.This model is based on the “brush-like”deformation of the hole wall,with the axial installation force predicted through force analysis and theoretical calculations,effectively overcoming the limitations of prior models that idealized the contact interface at the bolt-hole.The predictions generated by this theoretical model align closely with experimental data,confirming its efficacy in accurately forecasting the curve of installation force for interferencefit bolts during the static installation within the moderate interference-fit range.Additionally,a comprehensive analysis of the relationship between deformation of the hole wall and curves of installation force across small,moderate,and large interference-fit levels are presented.It is demonstrated that the degree of deformation within the moderate interference-fit range is more suitable than that in the small and large interference-fit ranges,making it a reliable alternative for installation force tests within this range during static installation.The moderate interference-fit domain[1.00%,1.24%]is established as a validated and optimal range of interference-fit bolts for the static installation. 展开更多
关键词 Axial installation force CFRP Contact interface Interference-fit bolt Predictive model
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A Novel Raman Spectrometer using Bessel-like Laser Beam for Homogeneous Phases and Interface Detections 认领 引用
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作者 Ning Chen Yuhui Li +3 位作者 Tianle Zhang Jin Yang Xiaoguo Zhou Shilin Liu 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2026年第3期318-327,I0004-I0006,共10页
Bessel beams,often referred to as“nondiffractive”light,have been successfully applied in numerous fields.In this study,we integrated a Bessel beam as the illumination source into a Raman spectrometer to enhance the ... Bessel beams,often referred to as“nondiffractive”light,have been successfully applied in numerous fields.In this study,we integrated a Bessel beam as the illumination source into a Raman spectrometer to enhance the detection of homogeneous phases and interfaces.By simulating optical path systems,we optimized the setup to fully utilize the multi-pixel array and maximize detection sensitivity.Compared to a conventional Gaussian-beam Raman spectrometer in the 90°-scattered configuration,the upgraded Raman spectrometer employing a Bessel-like beam demonstrated a nearly 6-fold improvement in sensitivity.Additionally,it significantly suppressed background scattering interferences in the low-frequency range,thus enhancing the clarity and accuracy of spectral data.Furthermore,the capability of this spectrometer for real-space Raman imaging of heterogeneous phase interfaces was verified.This advancement not only improves the sensitivity and precision of Raman measurements but also expands the potential applications of Raman spectroscopy in studying complex systems,such as interfaces and phase boundaries,with high spatial and spectral resolution. 展开更多
关键词 Raman spectroscopy Raman imaging Interface Bessel beam Gaussian beam
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Interface effect induced electron-deficient Ni sites for efficient glycerol electrooxidation 认领 引用
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作者 Lan Tang Ji Chen +5 位作者 Yucheng Wu Linxin Qi Xingyi Tian Ming Li Wenbin Wang Rongxing He 《Chinese Chemical Letters》 SCIE CAS CSCD 2026年第6期646-651,共6页
Glycerol oxidation reaction has got lots of attention in an electrocatalytic system of simultaneous hydrogen production and valuable chemicals generation.However,the lack of electrochemical dehydrogenation capability ... Glycerol oxidation reaction has got lots of attention in an electrocatalytic system of simultaneous hydrogen production and valuable chemicals generation.However,the lack of electrochemical dehydrogenation capability of the active phase is hard to deliver a large current density at a low potential.Furthermore,high selectivity of products is also still far from being completed due to the adsorption-desorption disequilibrium of glycerol and the obtained products,reducing the economic feasibility and limiting the practical application.Here,we propose a strategy to boost the electrocatalytic glycerol oxidation through electron-deficient Ni sites induced by electron transfer of heterojunction interface.Taking Ni3S2/Cu2S as a pre-catalysts,we demonstrate that the electron-deficient Ni site can favor the dehydrogenation of the active phase to facilitate the rapid transformation of Ni2+/Ni3+in the electrooxidation process of glycerol.Furthermore,electron deficient Ni sites balance competitive adsorption of active species,improving the activity and selectivity of glycerol oxidation.As expected,the electrocatalysts exhibit selectivity of 93.3%for formate at the 1.35 V,and require only 1.45 V to drive an industrial-level current densities of 600 mA/cm2.This work provides valuable insights into constructing highly active and selective electrocatalysts for organic electrosynthesis in hybrid water electrolysis. 展开更多
关键词 Electron-deficient site Heterojunction interface Formate Glycerol electrooxidation High selectivity
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Negative Excess-Energy Interfaces:A New Paradigm for Metal Strengthening Beyond Theoretical Limits 认领 引用
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作者 Song Tang Si Lan Xun-Li Wang 《Rare Metals》 SCIE EI CAS CSCD 2026年第1期856-858,共3页
For decades,refining grain or twin structures at the nanoscale has been the cornerstone strategy for enhancing metal strength[1].However,when structural dimensions shrink to below~10 nm,this approach hits an insurmoun... For decades,refining grain or twin structures at the nanoscale has been the cornerstone strategy for enhancing metal strength[1].However,when structural dimensions shrink to below~10 nm,this approach hits an insurmountable bottleneck,that is,material softening triggered by interface instability,which prevents further strength improvement[2-5].Now,writing in science,Li and colleagues introduce a novel strengthening approach based on nanoscale negative excess-energy interfaces(NEIs)that elevates the mechanical performance of nickelmolybdenum(Ni-Mo)alloys to an unprecedented level[6]. 展开更多
关键词 mechanical nanoscale metal strengthening interface instability mechanical performance negative excess energy interfaces grain twin structures enhancing metal strength howeverwhen
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