[Objectives]To study the process of Zhuang medicine Wuzhi Maotao Buxu Granule.[Methods]The orthogonal design method was used to optimize the best water extraction process with the amount of water,extraction time and e...[Objectives]To study the process of Zhuang medicine Wuzhi Maotao Buxu Granule.[Methods]The orthogonal design method was used to optimize the best water extraction process with the amount of water,extraction time and extraction times as factors and the dry extraction yield of granules as the indicators.The concentration process was screened and molding process and the pilot production were studied.[Results]The optimal water extraction process was as follows:soaked in water for 30 min,decocted twice-first with 10 times the amount of water for 1 h,then with 8 times the amount of water for 1 h.The extract was concentrated using a two-step method:initial concentration under reduced pressure,followed by secondary concentration at atmospheric pressure.Ethanol concentration was 85%,with dextrin as the filler.The product yield of three batches of Wuzhi Maotao Buxu Granule all exceeded 80%.[Conclusions]Wuzhi Maotao Buxu Granule was extracted using the water extraction method.Through the selection of concentration processes,research on granulation techniques,and pilot-scale production studies,the granules formed well with high yield,good fluidity,high efficiency,and suitability for large-scale production.展开更多
Pellet ores are recognized as an effective route for energy saving and carbon mitigation in ironmaking,yet systematic life cycle assessment(LCA)of pellet production remains limited.Thus,the environmental impacts and c...Pellet ores are recognized as an effective route for energy saving and carbon mitigation in ironmaking,yet systematic life cycle assessment(LCA)of pellet production remains limited.Thus,the environmental impacts and carbon-reduction potential of optimization measures across different pelletizing processes were quantified using a cradle-to-gate LCA approach.The results indicated that the predominant environmental burdens associated with pellet production were caused by iron concentrate,electricity,fuel,and direct emissions.Overall,the straight grate(SG)process exhibited lower impacts across multiple categories compared to the grate kiln(GK)process.The greenhouse gas(GHG)emissions from SG and GK were 118.51 and 146.78 kg CO2equivalent per 1000 kg of pellet ores,respectively.Sensitivity analysis revealed that iron ore concentrate,fuel,and electricity were the key factors in the pelletizing process.Compared to conventional levels,utilizing secondary resources,optimizing energy structure,and implementing advanced carbon capture and storage technologies could reduce GHG emissions from SG and GK to 32.89%and 34.81%,respectively.展开更多
The synergistic mechanism of multiple process parameters on the solidification structure of niobium containing austenitic stainless steel during continuous casting is complex,which seriously affects the quality of con...The synergistic mechanism of multiple process parameters on the solidification structure of niobium containing austenitic stainless steel during continuous casting is complex,which seriously affects the quality of continuous casting billets and seamless pipes.In order to optimize the quality of continuous casting billet,a finite element model of solidification and heat transfer in continuous casting process was established for the secondary cooling process of continuous casting billet.The control variable method was used to explore the influence of casting speed and superheat on the solidification process.At the same time,an orthogonal scheme was designed to study the coupling effect of multiple process parameters on the heat transfer and solidification state of continuous casting billets,and optimized process parameters were selected.The optimization results of process parameters were verified through production experiments,and it is found that the enrichment of coarse niobium compounds directly causes the initiation and propagation of inner wall cracks during the large deformation hot piercing of S30432 seamless tubes.Process parameter optimization,especially the synergistic effect of the decrease of superheat and increase of specific water flow promotes the grain refinement and expension of equiaxed crystal zone,thereby mitigating the segregation of Nb elements and improving the distribution of niobium compounds.展开更多
Ironmaking process(IP)is indispensable to modern iron and steel industry,where real-time monitoring is crucial for achieving high molten iron quality(MIQ)with low energy consumption.While neural network-based models s...Ironmaking process(IP)is indispensable to modern iron and steel industry,where real-time monitoring is crucial for achieving high molten iron quality(MIQ)with low energy consumption.While neural network-based models show some promising results,they are generally limited by non-negligible drawbacks such as interpretability issues of feature learning.To address these issues,we propose a novel concept based on the shallow-to-deep correlation network representation regression(Sh-to-De CNRR).Our approach,shallow correlation network representation regression(ShCNRR),combines neural network and canonical correlation analysis thoughts to generate explainable features via shallow correlation network representation(CNR).A twin inverse network is then derived to obtain the explicit model output,leveraging the shallow CNR.To capture deeper nonlinear information,we extend ShCNRR into a hierarchical deep correlation network representation regression(DeCNRR)model that features stacked neural networks,enabling us to learn deeper CNR from process data.The feasibility and advantages of our proposals are validated by theoretical derivations and practical IP cases,which contain one MIQ regression and three MIQ-related fault detection tasks.The results reveal that highly fused statistical and neural network models yield superior monitoring performance compared to current state-of-the-art models,while statistical tests verify the convincing feature mining.展开更多
We propose a new set of nuclear mass predictions based on multiple theoretical mass models.By employing Gaussian process regression with the Matern kernel,we achieved root-mean-square(rms)deviations below 100 keV for ...We propose a new set of nuclear mass predictions based on multiple theoretical mass models.By employing Gaussian process regression with the Matern kernel,we achieved root-mean-square(rms)deviations below 100 keV for the training dataset.The best-performing mass models achieved rms deviations below 150 keV for the new precise mass data from AME2020,whereas the ensemble average showed robust performance across the nuclear chart.Our approach uniquely combines:(1)systematic refinement of eight mass models through their residuals,(2)physics-informed features,including magic numbers,nucleon parity numbers,neutron excess,and nuclear collectivity,and(3)theory-to-theory validation demonstrating robust extrapolation capability.We find that the Matern kernel provides superior uncertainty quantification compared to the RBF kernel,with a length-scale analysis revealing enhanced inter-nuclei correlations.We provide complete mass predictions for all unknown nuclides in AME2020,offering valuable constraints for nuclear structure studies and astrophysical modeling when used with proper uncertainty propagation.展开更多
The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurode...The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurodegenerative diseases are characterized by the progressive loss of neuronal structure and function.展开更多
The multi-pass intermittent local loading process,which features a more flexible processing path,can further enhance the second material distribution during local loading,improve the formability of components,and redu...The multi-pass intermittent local loading process,which features a more flexible processing path,can further enhance the second material distribution during local loading,improve the formability of components,and reduce forming loads.However,the absence of compatible forming equipment makes it difficult to control the constraint in the unloaded zones during the forming process.This difficulty complicates coordination and control of deformation,particularly for asymmetric rib-web components.Additionally,the current implementation involves multi-fire heating,a long process flow,and high energy consumption,which limits the popularization and application of the local loading process.In this study,a new multi-pass local loading hydraulic forming apparatus that can quickly and reliably switch between heavy-load deformation and low-load constraint for different local loading sub-dies was developed.A 10-tonne laboratory prototype was developed,and the forming characteristics during the forming process as well as the response characteristics of the hydraulic system during the multi-pass intermittent local loading of rib-web component were investigated using numerical simulations and physical experiments.Results indicated that,compared to a whole loading process with the same initial geometry of billet,the total forming load(i.e.,the sum of loaded and restrained loads)is reduced by more than 40%with the local loading process,and by nearly 50%with multi-pass local loading.The multi-pass local loading process allows for more effective control of material flow compared to single-pass local loading,leading to improved cavity filling and reduced flow line disturbance.For a large-scale,complex titanium alloy bulkhead,the cavity filling problem was addressed by optimizing the multi-pass local loading path with an unequal thickness billet.The dynamic performance of the multi-pass local loading hydraulic system was found to be robust,with stable pressure transitions during motion and load switching for the sub-die(s).The dynamic characteristic of the hydraulic cylinder when switching from non-moving/unloaded state to a moving/loading state are consistent whether a load is present or not.However,the dynamic characteristics differ when switching from a moving/loading state to non-moving/unloaded state,showing opposite behavior.The developed hydraulic drive mechanism provides a way for implementation of multi-pass local loading without auxiliary operation and extra heating.The results of the study provide a foundation for the industrial production of large-scale,complex components with reduced force requirement and low-energy consumption.展开更多
Granular agricultural products constitute a staple food source for over 70%global population,are recognized as a core component within the food processing chain,and are accorded significant economic importance in inte...Granular agricultural products constitute a staple food source for over 70%global population,are recognized as a core component within the food processing chain,and are accorded significant economic importance in international trade.Inadequate desiccation during harvest seasons is associated with the facilitation of mold proliferation,induction of germination processes,and acceleration of product deterioration.These outcomes are manifested through compromised food security and incurred economic losses.Nevertheless,the porous structural characteristics inherent to granular crops,combined with the stress fission challenges encountered during dehydration processes,render alternative methods such as solarization and hot air drying frequently inadequate for meeting crop-specific drying requirements.In this study,the implementation and relative merits of microwave and infrared drying technologies for granular crops have been systematically examined.Subsequently,the enhanced drying efficiency and quality parameters achieved through microwave-hot air,infrared-hot air,and infrared-microwave hybrid drying systems are quantitatively demonstrated in comparison with conventional single-mode drying approaches.A comprehensive synthesis is presented regarding experimental findings and research priorities associated with microwave-vacuum,far-infrared vacuum,and fluidized bed drying applications.The developmental potential of emerging desiccation technologies-including radio frequency,ohmic,and heat pump-based systems-was critically evaluated through the comparative analysis of dehydration kinetics,energy efficiency metrics,and product quality indices.A theoretical framework was established for optimizing the novel drying equipment and operational parameters.This systematic investigation contributes substantively to the realization of energy-efficient,low-carbon,and quality-preserving drying objectives,thereby providing crucial technical support for global food security initiatives and sustainable agricultural practices.展开更多
Three-beam wire-feed laser cladding,which generates a uniform energy distribution with a wire vertically fed into the molten pool,is a promising additive manufacturing technology.In this study,an experimental investig...Three-beam wire-feed laser cladding,which generates a uniform energy distribution with a wire vertically fed into the molten pool,is a promising additive manufacturing technology.In this study,an experimental investigation and a statistical analysis of Ti-6Al-4V wire cladding using three-beam laser coaxial wire-feed cladding technology coupled with a 2 kW continuous fiber laser were carried out.The influences of the main parameters,including the laser power,wire feeding speed,and laser scanning speed,on the cladding geometry and process were investigated.The prediction models correlating the process parameters and clad geometry were developed via the response surface methodology(RSM).The models were checked using analysis of variance(ANOVA).Through optimization,the optimal parameters were achieved for the required clad with a width-to-height ratio of 5:1.A high-speed camera was used to investigate the cladding process under various process parameters.The laser power positively affected the widths of the molten pool and cladding layer.The molten pool and clad heights decreased with increases in laser power and scanning speed.Fine acicular martensite grains in the colony and basket-weave distributions were predominant in the cross-section of the cladding layer.The macrostructure investigation showed that the widths of columnar prior-β grains decreased with the increase in laser scanning speed.展开更多
Ship emissions significantly impact coastal air quality,with the Yangtze River Delta(YRD)region accounting for approximately 50%of China's total shipping emissions.Using the Community Multiscale Air Quality(CMAQ)m...Ship emissions significantly impact coastal air quality,with the Yangtze River Delta(YRD)region accounting for approximately 50%of China's total shipping emissions.Using the Community Multiscale Air Quality(CMAQ)model and process analysis(PA)tool,we quantitatively assessed how atmospheric processes(emissions,chemical reactions,transport,and deposition)contribute to PM2.5and O3,and the chemical pathways of O3formation due to ship emissions.Ship emissions significantly enhanced PM2.5concentrations(>5μg/m3)in the coastal areas of Jiangsu province and offshore regions,with diminishing inland effects.Ship-induced NO3-showed greater inland penetration compared to SO42-,which remained near the coast.In coastal cities,aerosol processes,rather than primary emissions,dominated PM2.5formation,highlighting the importance of secondary formation.O3responses varied spatially,showing coastal titration zones but inland enhancements.Process analysis revealed that vertical transport dominated O3distribution in coastal regions(5-10 ppb),whereas chemical processes showed strong negative contributions(below-10 ppb)along shipping routes.The impact exhibited pronounced diurnal variations,peaking during afternoon hours(14:00-17:00 local standard time(LST),up to 10 ppb/h)with morning titration effects(up to-7.5 ppb/h at 08:00 LST).The vertical profile analysis of shipping-related O3showed surface-level O3titration from ship NOxemissions,with impacts extending to higher layers through vertical mixing.Integrated reaction rate analysis revealed that effective O3control in shipping-influenced regions requires coordinated reduction of both NOxand VOCs.These findings provide insights for developing targeted control strategies,particularly for addressing the complex NOx-O3chemistry and secondary PM2.5formation.展开更多
Nanometallic materials have attracted wide research attention in the fabrication of functional devices,including flexible electronics circuits and high-sensitive sensors.Sintering of nanometallic materials is generall...Nanometallic materials have attracted wide research attention in the fabrication of functional devices,including flexible electronics circuits and high-sensitive sensors.Sintering of nanometallic materials is generally thought as an effective technology for the functional manufacturing,and the controllable sintering of nanometallic materials and its major mechanisms have long been a challenge.Here,an ultrafast laser processing strategy for Ag nanoparticles(NPs)is achieved by modulating plasmonic.The excitation mode of plasmon can be designed by laser parameters,including polarization with a specific crystal size.The atomic-scale ultrafast dynamics are revealed for understanding the sintering process and design of the sintered structures.The non-equilibrium energy transfer between electron and lattice and dynamic evolution of pressure are proved to be the foremost driving forces on the motion of atomic structures.Through research of plasmonic-induced electric field enhancement and non-uniform deposition of heat and in-situ observation of relative transmittance,mapping from atomic-scale structure to micro behavior is established.Based on plasmonic modulation and processing of Ag NPs,a machine learning combined flexible gesture sensor with high recognition accuracy is displayed.This work expands the knowledge of interactions between lasers and nanometallic materials and provides a method for designing functional devices for a wide range of applications.展开更多
In rock engineering,natural cracks in rock masses subjected to external loads tend to initiate and propagate,leading to potential safety hazards.To investigate the effect of cracking behavior on the mechanical propert...In rock engineering,natural cracks in rock masses subjected to external loads tend to initiate and propagate,leading to potential safety hazards.To investigate the effect of cracking behavior on the mechanical properties of rocks,the cracking processes of pre-cracked rocks have been extensively studied using numerical modeling methods.The peridynamics(PD)exhibits advantages over other numerical methods due to the absence of the requirements for remeshing and external crack growth criterion.However,for modeling pre-cracked rock cracking processes under impact,current PD implementations lack generally applicable rock constitutive models and impact contact models,which leads to difficulties in determining rock material parameters and efficiently calculating impact loads.This paper proposes a non-ordinary state-based peridynamics(NOSBPD)modeling method integrating the Drucker-Prager(DP)plasticity model and an efficient contact model to address the above problems.In the proposed method,the Drucker-Prager plasticity model is integrated into the NOSBPD,thereby equipping NOSBPD with the capability to accurately characterize the nonlinear stress-strain relationship inherent in rocks.An efficient contact model between particles and meshes is designed to calculate the impact loads,which is essentially a coupling method of PD with the finite element method(FEM).The effectiveness of the proposed NOSBPD modeling method is verified by comparison with other numerical methods and experiments.Experimental results indicate that the proposed method can effectively and accurately predict the 3D cracking processes of pre-cracked cracks under impact loading,and the maximum principal stress is the key driver behind wing crack formation in pre-cracked rocks.展开更多
The 2.5D process is widely utilized in modern industries,with multi-genus cross-sections increasingly encountered in both additive and subtractive manufacturing.Tool paths for multigenus shapes often suffer from disco...The 2.5D process is widely utilized in modern industries,with multi-genus cross-sections increasingly encountered in both additive and subtractive manufacturing.Tool paths for multigenus shapes often suffer from discontinuities that lead to frequent tool liftings,and selfintersections in offset paths,adversely affecting machining accuracy and efficiency.In this context,path topology,stepover uniformity,and degeneration of offset paths represent three fundamental concerns that must be considered in an integrated manner in 2.5D path planning for multi-genus shapes.This study proposes a tool path planning method based on combining of topological and geometric characteristics of medial axis transformation for the shape with multi-genus.A region segmentation strategy tailored to multi-genus shapes is first introduced to prevent global selfintersections in equidistant offset paths.Subsequently,the graph structure of the segmented shape is extracted,and the minimization of tool liftings is formulated as a minimum path cover problem in an undirected graph.A Fermat-spiral-like path topology is adopted within sub-regions to preserve the connectivity of graph and ensure smooth transitions between successive layers of contourparallel paths.Numerical and physical experiment results confirm the proposed method's effectiveness in maintaining stepover uniformity,avoiding degeneration of global self-intersections,and ensuring path connectivity.展开更多
Underground engineering projects such as deep tunnel excavation often encounter rockburst disasters accompanied by numerous microseismic events.Rapid interpretation of microseismic signals is crucial for the timely id...Underground engineering projects such as deep tunnel excavation often encounter rockburst disasters accompanied by numerous microseismic events.Rapid interpretation of microseismic signals is crucial for the timely identification of rockbursts.However,conventional processing encompasses multi-step workflows,including classification,denoising,picking,locating,and computational analysis,coupled with manual intervention,which collectively compromise the reliability of early warnings.To address these challenges,this study innovatively proposes the“microseismic stethoscope"-a multi-task machine learning and deep learning model designed for the automated processing of massive microseismic signals.This model efficiently extracts three key parameters that are necessary for recognizing rockburst disasters:rupture location,microseismic energy,and moment magnitude.Specifically,the model extracts raw waveform features from three dedicated sub-networks:a classifier for source zone classification,and two regressors for microseismic energy and moment magnitude estimation.This model demonstrates superior efficiency compared to traditional processing and semi-automated processing,reducing per-event processing time from 0.71 s to 0.49 s to merely 0.036 s.It concurrently achieves 98%accuracy in source zone classification,with microseismic energy and moment magnitude estimation errors of 0.13 and 0.05,respectively.This model has been well applied and validated in the Daxiagu Tunnel case in Sichuan,China.The application results indicate that the model is as accurate as traditional methods in determining source parameters,and thus can be used to identify potential geomechanical processes of rockburst disasters.By enhancing the signal processing reliability of microseismic events,the proposed model in this study presents a significant advancement in the identification of rockburst disasters.展开更多
Arctic warming has been widely documented, yet the relative contributions of processes controlling surface air temperature(SAT) and surface temperature(ST) warming remain insufficiently quantified, particularly betwee...Arctic warming has been widely documented, yet the relative contributions of processes controlling surface air temperature(SAT) and surface temperature(ST) warming remain insufficiently quantified, particularly between warm and cold seasons. Here, we use multiple reanalysis datasets to quantify Arctic SAT and ST warming from 1979 to 2021 through thermodynamic and surface energy budget analyses, with a focus on the seasonal contrast between warm season and cold season. We show that SAT warming in both seasons is primarily linked to an increase in the diabatic heating residual associated with surface warming, whereas cold season SAT warming is additionally enhanced by strengthened warm advection, which accounts for 33% of the total SAT increase. ST warming exhibits a stronger seasonal contrast. In the warm season, ST warming is driven jointly by enhanced downward longwave radiation, mainly associated with increased atmospheric water vapor, and sea ice albedo feedback, contributing 27% and 33% of the ST increase, respectively. In the cold season, ST warming is dominated by enhanced downward longwave radiation, with atmospheric water vapor, mid-level cloud cover, and a residual term mainly related to external greenhouse gas forcing contributing 36%, 16%, and 10%, respectively. The Arctic Ocean further modulates this seasonality by absorbing heat in the warm season and releasing it in the cold season, contributing 21% to cold season ST warming and providing an additional heat source for the lower atmosphere. These results demonstrate that recent Arctic warming cannot be interpreted from SAT or ST alone, but reflects seasonally distinct coupling among atmospheric heat transport, radiative feedbacks, sea ice loss, and ocean heat storage and release.展开更多
Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operato...Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operator training,etc.;thus,a hierarchical digital twin would be a comprehensive solution to that.In this study,a novel and general framework of the digital twin is proposed for operations in process industry.With the hierarchical structure,the framework can handle various tasks driven by different roles in process industry,including managers,engineers,and operators.To complete these tasks,the framework consists of three modules:OAS(Operation Analysis System),OMS(Operation Monitoring System),and OTS(Operator Training System).Each module focuses on one unique type of demand from the staff,as well as interactions among them enabling efficient data sharing.Based on the hierarchical framework,a digital twin system is applied for one complex industrial nitration process,which successfully enhances the operation efficiency and safety in several industrial scenarios with different demands.展开更多
In order to break through the limitations of the traditional hazard and operability(HAZOP)analysis,this study established a gray evaluation model based on gray theory for the riskiness ranking of deviations and semi-q...In order to break through the limitations of the traditional hazard and operability(HAZOP)analysis,this study established a gray evaluation model based on gray theory for the riskiness ranking of deviations and semi-quantitative analysis of risk levels.A quantitative HAZOP analysis combining HAZOP with Aspen Plus,Aspen Dynamics,Fault Tree Analysis(FTA),Risk Matrix and Layer of Protection Analysis(LOPA)was performed for high risk deviations.The dynamic model of the methanol washing unit in the rectisol process was established by Aspen Dynamics and the effects of different deviations on the risk indicators and operability indicators were investigated.Then,the risk of deviations was ranked according to the simulation results and the high-risk deviations were identified.Subsequently,the sensitivity analysis module of Aspen Plus software was used to calculate the fluctuationrange of highrisk deviations,whose results were imported into Aspen Dynamics to simulate and analyze the risk level of accidents,and then FTA was used to quantify the probability of accidents.Synchronizing the two to the risk matrix determined the deviations to have initial risk ratings of 10 and 15,both of which are high-risk deviations.The HAZOP quantitative analysis report is finalizedafter reducing the residual risk level of the deviation to 9(low risk)through LOPA analysis.The results of the case study showed that the method can verify the accuracy of the gray evaluation model to a certain extent,and the quantitative HAZOP analysis report is of guiding significancefor actual production.展开更多
Benzohydroxamic acid(BHA)occurs as recalcitrant organic pollutant discharged from mining industry.While Fenton-like oxidation based on peroxymonosulfate(PMS)has been extensively applied for organic contamination mitig...Benzohydroxamic acid(BHA)occurs as recalcitrant organic pollutant discharged from mining industry.While Fenton-like oxidation based on peroxymonosulfate(PMS)has been extensively applied for organic contamination mitigation,its conventional reaction pathway dependent on free radicals needs high energy input with elevated carbon emission.Here,we meticulously developed a novel single-atom catalyst featuring Co-N4coordination(Cox@NC)to initiate a non-radical Fenton-like oxidation for BHA treatment.Results showed single-atom Co-N4with the considerable Co content(>2 wt%)and quantitative N coordination displayed exceptional reactivity to activate PMS for BHA degradation with a turnover frequency>16 min-1.Such single-atom Co-N4formed a surface-reactive complexes with mild oxidation potential by coordinating with PMS to mediate electron transfer for oxidation of BHA.The mediated ETP further triggered polymerization transformation pathway of BHA through formation and coupling of phenoxylike radicals,resulting in a considerable recovery yield of BHA polymers(~43%)and superior utilization efficiency of PMS(~434%).Combined with ultrahigh-resolution mass analysis,the identified polymerized products illustrated the related polymerization mechanisms of BHA including hydroxylation,monomer radical generation,dimerization,and chain extension.Such Fenton-like catalysis of single-atom Co-N4exhibited more remarkable application potentials in mineral processing wastewater treatment compared to traditional Fenton reaction,reducing oxidant consumption and increasing organic carbon recovery.This study enhances development of resource-efficient Fenton-like oxidation technologies for mineral processing wastewater treatment.展开更多
With the complexity and intelligence of the industrial process,the identificationof faults in the actual process plays a crucial role in ensuring production safety.The traditional fault identificationstrategies have t...With the complexity and intelligence of the industrial process,the identificationof faults in the actual process plays a crucial role in ensuring production safety.The traditional fault identificationstrategies have the problem that similar characterized faults are unable to be accurately identified.Motivated by the limitations,a novel sample-optimized adaptive perceptual enhanced graph neural network(SOAPEGNN)for large-scale process fault identificationis proposed.Initially,process mechanism knowledge and process data correlation are injected into the modeling approach through graph neural networks,and the transmission of information based on the enhanced attention mechanism is introduced to describe the quantitative relationships between process variables at a fine-grainedlevel based on the adaptive perception strategy.Subsequently,to achieve better intra-class compactness and inter-class separability in feature representation,our designed sample-optimized feature processing strategy(SOFPS)is applied.Furthermore,to enhance the robustness and generalization capability of the model during training,a label smoothing regularization(LSR)strategy is incorporated.This approach effectively mitigates the risk of overfittingby introducing a degree of uncertainty into the label space,thereby encouraging the model to learn more discriminative and stable features.Ultimately,the efficacy and superiority of the SOAP-EGNN algorithm are thoroughly validated through comprehensive simulation experiments conducted on the Tennessee Eastman process(TEP).展开更多
To improve the overall magnetic properties of Sm(CoFeCuZr)zsintered magnets,a dual-alloy sintering process that involves mixing high-iron,low-copper powders with low-iron,high-copper powders was systematically inve...To improve the overall magnetic properties of Sm(CoFeCuZr)zsintered magnets,a dual-alloy sintering process that involves mixing high-iron,low-copper powders with low-iron,high-copper powders was systematically investigated.The results demonstrate that this method significantly improves the Cu-lean phenomenon at the grain boundaries,achieves multiscale uniform microstructures,greatly enhances the pinning field strength,and ultimately produces a high-performance dual-alloy magnet with a maximum energy product((BH)max)exceeding 240 kJ/m3and an intrinsic coercivity(Hcj)exceeding 2400 kA/m.In particular,when 35 wt.%of low-iron,high-copper alloy powder is incorporated,the dual-alloy magnet achieves a remanence of 1.13 T,Hcjof 2691.2 kA/m and(BH)maxof 248 kJ/m3.To evaluate the overall magnetic performance,the sum of Hcj(in kA/m)and(BH)max(in kJ/m3)is used as a combined parameter,yielding a value of 2939.2.Compared with single-alloy magnets of the same composition,the dual-alloy sintering process yields magnets with a more uniform elemental distribution and superior magnetic properties.展开更多
基金Supported by Key R&D Projects of Guangxi(Guike AB25069063)Guangxi Zhuang Autonomous Region Administration of Traditional Chinese Medicine Scientific Research Project(GXZYA20240186)+2 种基金State Administration of Traditional Chinese Medicine High-level Key Discipline Construction Project of Traditional Chinese Medicine-Ethnic Minority Pharmacy(Zhuang Pharmacy)(zyyzdxk-2023165)Young Talent Training Project of Guangxi International Zhuang Medicine Hospital(2022001)Construction Project of the Instructor(Qin Zujie)for the Inheritance of the Academic Experience of the Seventh Batch of National Old Chinese Medicine Experts(Guo Zhong Yi Yao Ren Jiao Han(2022)76).
摘要[Objectives]To study the process of Zhuang medicine Wuzhi Maotao Buxu Granule.[Methods]The orthogonal design method was used to optimize the best water extraction process with the amount of water,extraction time and extraction times as factors and the dry extraction yield of granules as the indicators.The concentration process was screened and molding process and the pilot production were studied.[Results]The optimal water extraction process was as follows:soaked in water for 30 min,decocted twice-first with 10 times the amount of water for 1 h,then with 8 times the amount of water for 1 h.The extract was concentrated using a two-step method:initial concentration under reduced pressure,followed by secondary concentration at atmospheric pressure.Ethanol concentration was 85%,with dextrin as the filler.The product yield of three batches of Wuzhi Maotao Buxu Granule all exceeded 80%.[Conclusions]Wuzhi Maotao Buxu Granule was extracted using the water extraction method.Through the selection of concentration processes,research on granulation techniques,and pilot-scale production studies,the granules formed well with high yield,good fluidity,high efficiency,and suitability for large-scale production.
基金financial support from the Basic Science Center Project for National Natural Science Foundation of China(No.72088101)the Science and Technology Innovation Program of Hunan Province(Nos.2023RC1025 and 2024RC3022).
摘要Pellet ores are recognized as an effective route for energy saving and carbon mitigation in ironmaking,yet systematic life cycle assessment(LCA)of pellet production remains limited.Thus,the environmental impacts and carbon-reduction potential of optimization measures across different pelletizing processes were quantified using a cradle-to-gate LCA approach.The results indicated that the predominant environmental burdens associated with pellet production were caused by iron concentrate,electricity,fuel,and direct emissions.Overall,the straight grate(SG)process exhibited lower impacts across multiple categories compared to the grate kiln(GK)process.The greenhouse gas(GHG)emissions from SG and GK were 118.51 and 146.78 kg CO2equivalent per 1000 kg of pellet ores,respectively.Sensitivity analysis revealed that iron ore concentrate,fuel,and electricity were the key factors in the pelletizing process.Compared to conventional levels,utilizing secondary resources,optimizing energy structure,and implementing advanced carbon capture and storage technologies could reduce GHG emissions from SG and GK to 32.89%and 34.81%,respectively.
基金supported by the National Natural Science Foundation of China(Nos.U25A20282,U23A20628,52375394,52305429)the Major Project of Science and Technology in Shanxi(Nos.202501050201012,202301050201004)。
摘要The synergistic mechanism of multiple process parameters on the solidification structure of niobium containing austenitic stainless steel during continuous casting is complex,which seriously affects the quality of continuous casting billets and seamless pipes.In order to optimize the quality of continuous casting billet,a finite element model of solidification and heat transfer in continuous casting process was established for the secondary cooling process of continuous casting billet.The control variable method was used to explore the influence of casting speed and superheat on the solidification process.At the same time,an orthogonal scheme was designed to study the coupling effect of multiple process parameters on the heat transfer and solidification state of continuous casting billets,and optimized process parameters were selected.The optimization results of process parameters were verified through production experiments,and it is found that the enrichment of coarse niobium compounds directly causes the initiation and propagation of inner wall cracks during the large deformation hot piercing of S30432 seamless tubes.Process parameter optimization,especially the synergistic effect of the decrease of superheat and increase of specific water flow promotes the grain refinement and expension of equiaxed crystal zone,thereby mitigating the segregation of Nb elements and improving the distribution of niobium compounds.
基金supported in part by the Pioneer Research and Development Program of Zhejiang(2025C01021)Zhejiang Province Postdoctoral Research Project Selection Fund(ZJ2025061)+3 种基金the National Science and Technology Major Project-Intelligent Manufacturing Systems and Robotics of China(2025ZD1602000,2025ZD1601800)the National Natural Science Foundation of China(61933015,62273030,62573387)the Natural Science Foundation of Zhejiang province,China(LY24F030004)the Fundamental Research Funds of Zhejiang Sci-Tech University(25222139-Y)。
摘要Ironmaking process(IP)is indispensable to modern iron and steel industry,where real-time monitoring is crucial for achieving high molten iron quality(MIQ)with low energy consumption.While neural network-based models show some promising results,they are generally limited by non-negligible drawbacks such as interpretability issues of feature learning.To address these issues,we propose a novel concept based on the shallow-to-deep correlation network representation regression(Sh-to-De CNRR).Our approach,shallow correlation network representation regression(ShCNRR),combines neural network and canonical correlation analysis thoughts to generate explainable features via shallow correlation network representation(CNR).A twin inverse network is then derived to obtain the explicit model output,leveraging the shallow CNR.To capture deeper nonlinear information,we extend ShCNRR into a hierarchical deep correlation network representation regression(DeCNRR)model that features stacked neural networks,enabling us to learn deeper CNR from process data.The feasibility and advantages of our proposals are validated by theoretical derivations and practical IP cases,which contain one MIQ regression and three MIQ-related fault detection tasks.The results reveal that highly fused statistical and neural network models yield superior monitoring performance compared to current state-of-the-art models,while statistical tests verify the convincing feature mining.
基金supported by the Key R&D Program of China(No.2021YFA1601500)the Talent Support Project of Guangdong Program(No.2023TQ07A872)the U.S.D.O.E contract DEAC05-00OR22725。
摘要We propose a new set of nuclear mass predictions based on multiple theoretical mass models.By employing Gaussian process regression with the Matern kernel,we achieved root-mean-square(rms)deviations below 100 keV for the training dataset.The best-performing mass models achieved rms deviations below 150 keV for the new precise mass data from AME2020,whereas the ensemble average showed robust performance across the nuclear chart.Our approach uniquely combines:(1)systematic refinement of eight mass models through their residuals,(2)physics-informed features,including magic numbers,nucleon parity numbers,neutron excess,and nuclear collectivity,and(3)theory-to-theory validation demonstrating robust extrapolation capability.We find that the Matern kernel provides superior uncertainty quantification compared to the RBF kernel,with a length-scale analysis revealing enhanced inter-nuclei correlations.We provide complete mass predictions for all unknown nuclides in AME2020,offering valuable constraints for nuclear structure studies and astrophysical modeling when used with proper uncertainty propagation.
摘要The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurodegenerative diseases are characterized by the progressive loss of neuronal structure and function.
基金the supports of the National Natural Science Foundation of China(Grant No.52375378)。
摘要The multi-pass intermittent local loading process,which features a more flexible processing path,can further enhance the second material distribution during local loading,improve the formability of components,and reduce forming loads.However,the absence of compatible forming equipment makes it difficult to control the constraint in the unloaded zones during the forming process.This difficulty complicates coordination and control of deformation,particularly for asymmetric rib-web components.Additionally,the current implementation involves multi-fire heating,a long process flow,and high energy consumption,which limits the popularization and application of the local loading process.In this study,a new multi-pass local loading hydraulic forming apparatus that can quickly and reliably switch between heavy-load deformation and low-load constraint for different local loading sub-dies was developed.A 10-tonne laboratory prototype was developed,and the forming characteristics during the forming process as well as the response characteristics of the hydraulic system during the multi-pass intermittent local loading of rib-web component were investigated using numerical simulations and physical experiments.Results indicated that,compared to a whole loading process with the same initial geometry of billet,the total forming load(i.e.,the sum of loaded and restrained loads)is reduced by more than 40%with the local loading process,and by nearly 50%with multi-pass local loading.The multi-pass local loading process allows for more effective control of material flow compared to single-pass local loading,leading to improved cavity filling and reduced flow line disturbance.For a large-scale,complex titanium alloy bulkhead,the cavity filling problem was addressed by optimizing the multi-pass local loading path with an unequal thickness billet.The dynamic performance of the multi-pass local loading hydraulic system was found to be robust,with stable pressure transitions during motion and load switching for the sub-die(s).The dynamic characteristic of the hydraulic cylinder when switching from non-moving/unloaded state to a moving/loading state are consistent whether a load is present or not.However,the dynamic characteristics differ when switching from a moving/loading state to non-moving/unloaded state,showing opposite behavior.The developed hydraulic drive mechanism provides a way for implementation of multi-pass local loading without auxiliary operation and extra heating.The results of the study provide a foundation for the industrial production of large-scale,complex components with reduced force requirement and low-energy consumption.
摘要Granular agricultural products constitute a staple food source for over 70%global population,are recognized as a core component within the food processing chain,and are accorded significant economic importance in international trade.Inadequate desiccation during harvest seasons is associated with the facilitation of mold proliferation,induction of germination processes,and acceleration of product deterioration.These outcomes are manifested through compromised food security and incurred economic losses.Nevertheless,the porous structural characteristics inherent to granular crops,combined with the stress fission challenges encountered during dehydration processes,render alternative methods such as solarization and hot air drying frequently inadequate for meeting crop-specific drying requirements.In this study,the implementation and relative merits of microwave and infrared drying technologies for granular crops have been systematically examined.Subsequently,the enhanced drying efficiency and quality parameters achieved through microwave-hot air,infrared-hot air,and infrared-microwave hybrid drying systems are quantitatively demonstrated in comparison with conventional single-mode drying approaches.A comprehensive synthesis is presented regarding experimental findings and research priorities associated with microwave-vacuum,far-infrared vacuum,and fluidized bed drying applications.The developmental potential of emerging desiccation technologies-including radio frequency,ohmic,and heat pump-based systems-was critically evaluated through the comparative analysis of dehydration kinetics,energy efficiency metrics,and product quality indices.A theoretical framework was established for optimizing the novel drying equipment and operational parameters.This systematic investigation contributes substantively to the realization of energy-efficient,low-carbon,and quality-preserving drying objectives,thereby providing crucial technical support for global food security initiatives and sustainable agricultural practices.
基金Supported by the National Natural Science Foundation of China(Grant Nos.62173239,61903268)Suzhou Vocational Institute of Industrial Technology Foundation(Grant Nos.2024kyqd003,2021kyqd005 and 2022kypy09).
摘要Three-beam wire-feed laser cladding,which generates a uniform energy distribution with a wire vertically fed into the molten pool,is a promising additive manufacturing technology.In this study,an experimental investigation and a statistical analysis of Ti-6Al-4V wire cladding using three-beam laser coaxial wire-feed cladding technology coupled with a 2 kW continuous fiber laser were carried out.The influences of the main parameters,including the laser power,wire feeding speed,and laser scanning speed,on the cladding geometry and process were investigated.The prediction models correlating the process parameters and clad geometry were developed via the response surface methodology(RSM).The models were checked using analysis of variance(ANOVA).Through optimization,the optimal parameters were achieved for the required clad with a width-to-height ratio of 5:1.A high-speed camera was used to investigate the cladding process under various process parameters.The laser power positively affected the widths of the molten pool and cladding layer.The molten pool and clad heights decreased with increases in laser power and scanning speed.Fine acicular martensite grains in the colony and basket-weave distributions were predominant in the cross-section of the cladding layer.The macrostructure investigation showed that the widths of columnar prior-β grains decreased with the increase in laser scanning speed.
基金supported by the National Key Research and Development Program of China(No.2022YFC3700703)。
摘要Ship emissions significantly impact coastal air quality,with the Yangtze River Delta(YRD)region accounting for approximately 50%of China's total shipping emissions.Using the Community Multiscale Air Quality(CMAQ)model and process analysis(PA)tool,we quantitatively assessed how atmospheric processes(emissions,chemical reactions,transport,and deposition)contribute to PM2.5and O3,and the chemical pathways of O3formation due to ship emissions.Ship emissions significantly enhanced PM2.5concentrations(>5μg/m3)in the coastal areas of Jiangsu province and offshore regions,with diminishing inland effects.Ship-induced NO3-showed greater inland penetration compared to SO42-,which remained near the coast.In coastal cities,aerosol processes,rather than primary emissions,dominated PM2.5formation,highlighting the importance of secondary formation.O3responses varied spatially,showing coastal titration zones but inland enhancements.Process analysis revealed that vertical transport dominated O3distribution in coastal regions(5-10 ppb),whereas chemical processes showed strong negative contributions(below-10 ppb)along shipping routes.The impact exhibited pronounced diurnal variations,peaking during afternoon hours(14:00-17:00 local standard time(LST),up to 10 ppb/h)with morning titration effects(up to-7.5 ppb/h at 08:00 LST).The vertical profile analysis of shipping-related O3showed surface-level O3titration from ship NOxemissions,with impacts extending to higher layers through vertical mixing.Integrated reaction rate analysis revealed that effective O3control in shipping-influenced regions requires coordinated reduction of both NOxand VOCs.These findings provide insights for developing targeted control strategies,particularly for addressing the complex NOx-O3chemistry and secondary PM2.5formation.
基金supported by the National Natural Science Foundation of China(52575510)the National Key R&D Program of China(2024YFB4609801).
摘要Nanometallic materials have attracted wide research attention in the fabrication of functional devices,including flexible electronics circuits and high-sensitive sensors.Sintering of nanometallic materials is generally thought as an effective technology for the functional manufacturing,and the controllable sintering of nanometallic materials and its major mechanisms have long been a challenge.Here,an ultrafast laser processing strategy for Ag nanoparticles(NPs)is achieved by modulating plasmonic.The excitation mode of plasmon can be designed by laser parameters,including polarization with a specific crystal size.The atomic-scale ultrafast dynamics are revealed for understanding the sintering process and design of the sintered structures.The non-equilibrium energy transfer between electron and lattice and dynamic evolution of pressure are proved to be the foremost driving forces on the motion of atomic structures.Through research of plasmonic-induced electric field enhancement and non-uniform deposition of heat and in-situ observation of relative transmittance,mapping from atomic-scale structure to micro behavior is established.Based on plasmonic modulation and processing of Ag NPs,a machine learning combined flexible gesture sensor with high recognition accuracy is displayed.This work expands the knowledge of interactions between lasers and nanometallic materials and provides a method for designing functional devices for a wide range of applications.
基金support from the National Natural Science Foundation of China(Grant Nos.42277161 and 42230709).
摘要In rock engineering,natural cracks in rock masses subjected to external loads tend to initiate and propagate,leading to potential safety hazards.To investigate the effect of cracking behavior on the mechanical properties of rocks,the cracking processes of pre-cracked rocks have been extensively studied using numerical modeling methods.The peridynamics(PD)exhibits advantages over other numerical methods due to the absence of the requirements for remeshing and external crack growth criterion.However,for modeling pre-cracked rock cracking processes under impact,current PD implementations lack generally applicable rock constitutive models and impact contact models,which leads to difficulties in determining rock material parameters and efficiently calculating impact loads.This paper proposes a non-ordinary state-based peridynamics(NOSBPD)modeling method integrating the Drucker-Prager(DP)plasticity model and an efficient contact model to address the above problems.In the proposed method,the Drucker-Prager plasticity model is integrated into the NOSBPD,thereby equipping NOSBPD with the capability to accurately characterize the nonlinear stress-strain relationship inherent in rocks.An efficient contact model between particles and meshes is designed to calculate the impact loads,which is essentially a coupling method of PD with the finite element method(FEM).The effectiveness of the proposed NOSBPD modeling method is verified by comparison with other numerical methods and experiments.Experimental results indicate that the proposed method can effectively and accurately predict the 3D cracking processes of pre-cracked cracks under impact loading,and the maximum principal stress is the key driver behind wing crack formation in pre-cracked rocks.
基金supported by the Beijing Natural Science Foundation,China(No.Z240002)the National Natural Science Foundation of China(Nos.62102013,12171023,and 12001028)。
摘要The 2.5D process is widely utilized in modern industries,with multi-genus cross-sections increasingly encountered in both additive and subtractive manufacturing.Tool paths for multigenus shapes often suffer from discontinuities that lead to frequent tool liftings,and selfintersections in offset paths,adversely affecting machining accuracy and efficiency.In this context,path topology,stepover uniformity,and degeneration of offset paths represent three fundamental concerns that must be considered in an integrated manner in 2.5D path planning for multi-genus shapes.This study proposes a tool path planning method based on combining of topological and geometric characteristics of medial axis transformation for the shape with multi-genus.A region segmentation strategy tailored to multi-genus shapes is first introduced to prevent global selfintersections in equidistant offset paths.Subsequently,the graph structure of the segmented shape is extracted,and the minimization of tool liftings is formulated as a minimum path cover problem in an undirected graph.A Fermat-spiral-like path topology is adopted within sub-regions to preserve the connectivity of graph and ensure smooth transitions between successive layers of contourparallel paths.Numerical and physical experiment results confirm the proposed method's effectiveness in maintaining stepover uniformity,avoiding degeneration of global self-intersections,and ensuring path connectivity.
基金supported by the National Natural Science Foundation of China(Grant Nos.42130719 and 42177173)the Doctoral Direct Train Project of Chongqing Natural Science Foundation(Grant No.CSTB2023NSCQ-BSX0029).
摘要Underground engineering projects such as deep tunnel excavation often encounter rockburst disasters accompanied by numerous microseismic events.Rapid interpretation of microseismic signals is crucial for the timely identification of rockbursts.However,conventional processing encompasses multi-step workflows,including classification,denoising,picking,locating,and computational analysis,coupled with manual intervention,which collectively compromise the reliability of early warnings.To address these challenges,this study innovatively proposes the“microseismic stethoscope"-a multi-task machine learning and deep learning model designed for the automated processing of massive microseismic signals.This model efficiently extracts three key parameters that are necessary for recognizing rockburst disasters:rupture location,microseismic energy,and moment magnitude.Specifically,the model extracts raw waveform features from three dedicated sub-networks:a classifier for source zone classification,and two regressors for microseismic energy and moment magnitude estimation.This model demonstrates superior efficiency compared to traditional processing and semi-automated processing,reducing per-event processing time from 0.71 s to 0.49 s to merely 0.036 s.It concurrently achieves 98%accuracy in source zone classification,with microseismic energy and moment magnitude estimation errors of 0.13 and 0.05,respectively.This model has been well applied and validated in the Daxiagu Tunnel case in Sichuan,China.The application results indicate that the model is as accurate as traditional methods in determining source parameters,and thus can be used to identify potential geomechanical processes of rockburst disasters.By enhancing the signal processing reliability of microseismic events,the proposed model in this study presents a significant advancement in the identification of rockburst disasters.
基金supported by the National Key Research and Development Program of China (Grant no. 2023YFE0123800)the Shanghai Pilot Program for Basic Research-Fudan University,China (Grant no. 22TQ007)+1 种基金supported by the Shanghai Frontiers Science Center of Polar Science,China (Grant no. SOO2026-05)the Postdoctoral Fellowship Program of China Postdoctoral Science Foundation (CPSF)(Grant no. GZB20250074)。
摘要Arctic warming has been widely documented, yet the relative contributions of processes controlling surface air temperature(SAT) and surface temperature(ST) warming remain insufficiently quantified, particularly between warm and cold seasons. Here, we use multiple reanalysis datasets to quantify Arctic SAT and ST warming from 1979 to 2021 through thermodynamic and surface energy budget analyses, with a focus on the seasonal contrast between warm season and cold season. We show that SAT warming in both seasons is primarily linked to an increase in the diabatic heating residual associated with surface warming, whereas cold season SAT warming is additionally enhanced by strengthened warm advection, which accounts for 33% of the total SAT increase. ST warming exhibits a stronger seasonal contrast. In the warm season, ST warming is driven jointly by enhanced downward longwave radiation, mainly associated with increased atmospheric water vapor, and sea ice albedo feedback, contributing 27% and 33% of the ST increase, respectively. In the cold season, ST warming is dominated by enhanced downward longwave radiation, with atmospheric water vapor, mid-level cloud cover, and a residual term mainly related to external greenhouse gas forcing contributing 36%, 16%, and 10%, respectively. The Arctic Ocean further modulates this seasonality by absorbing heat in the warm season and releasing it in the cold season, contributing 21% to cold season ST warming and providing an additional heat source for the lower atmosphere. These results demonstrate that recent Arctic warming cannot be interpreted from SAT or ST alone, but reflects seasonally distinct coupling among atmospheric heat transport, radiative feedbacks, sea ice loss, and ocean heat storage and release.
基金support of the“Pioneer”and“Leading Goose”Research&Development Program of Zhejiang(2024C01028)the State Key Laboratory of Industrial Control Technology,China(ICT2024C04)are gratefully acknowledged.
摘要Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operator training,etc.;thus,a hierarchical digital twin would be a comprehensive solution to that.In this study,a novel and general framework of the digital twin is proposed for operations in process industry.With the hierarchical structure,the framework can handle various tasks driven by different roles in process industry,including managers,engineers,and operators.To complete these tasks,the framework consists of three modules:OAS(Operation Analysis System),OMS(Operation Monitoring System),and OTS(Operator Training System).Each module focuses on one unique type of demand from the staff,as well as interactions among them enabling efficient data sharing.Based on the hierarchical framework,a digital twin system is applied for one complex industrial nitration process,which successfully enhances the operation efficiency and safety in several industrial scenarios with different demands.
基金supported by the National Nature Science Foundation of China(U1710101)the Shanxi Science and Technology Service Co.Ltd.,China.
摘要In order to break through the limitations of the traditional hazard and operability(HAZOP)analysis,this study established a gray evaluation model based on gray theory for the riskiness ranking of deviations and semi-quantitative analysis of risk levels.A quantitative HAZOP analysis combining HAZOP with Aspen Plus,Aspen Dynamics,Fault Tree Analysis(FTA),Risk Matrix and Layer of Protection Analysis(LOPA)was performed for high risk deviations.The dynamic model of the methanol washing unit in the rectisol process was established by Aspen Dynamics and the effects of different deviations on the risk indicators and operability indicators were investigated.Then,the risk of deviations was ranked according to the simulation results and the high-risk deviations were identified.Subsequently,the sensitivity analysis module of Aspen Plus software was used to calculate the fluctuationrange of highrisk deviations,whose results were imported into Aspen Dynamics to simulate and analyze the risk level of accidents,and then FTA was used to quantify the probability of accidents.Synchronizing the two to the risk matrix determined the deviations to have initial risk ratings of 10 and 15,both of which are high-risk deviations.The HAZOP quantitative analysis report is finalizedafter reducing the residual risk level of the deviation to 9(low risk)through LOPA analysis.The results of the case study showed that the method can verify the accuracy of the gray evaluation model to a certain extent,and the quantitative HAZOP analysis report is of guiding significancefor actual production.
基金supported by the National Key Research and Development Program of China(No.2023YFC3207300)。
摘要Benzohydroxamic acid(BHA)occurs as recalcitrant organic pollutant discharged from mining industry.While Fenton-like oxidation based on peroxymonosulfate(PMS)has been extensively applied for organic contamination mitigation,its conventional reaction pathway dependent on free radicals needs high energy input with elevated carbon emission.Here,we meticulously developed a novel single-atom catalyst featuring Co-N4coordination(Cox@NC)to initiate a non-radical Fenton-like oxidation for BHA treatment.Results showed single-atom Co-N4with the considerable Co content(>2 wt%)and quantitative N coordination displayed exceptional reactivity to activate PMS for BHA degradation with a turnover frequency>16 min-1.Such single-atom Co-N4formed a surface-reactive complexes with mild oxidation potential by coordinating with PMS to mediate electron transfer for oxidation of BHA.The mediated ETP further triggered polymerization transformation pathway of BHA through formation and coupling of phenoxylike radicals,resulting in a considerable recovery yield of BHA polymers(~43%)and superior utilization efficiency of PMS(~434%).Combined with ultrahigh-resolution mass analysis,the identified polymerized products illustrated the related polymerization mechanisms of BHA including hydroxylation,monomer radical generation,dimerization,and chain extension.Such Fenton-like catalysis of single-atom Co-N4exhibited more remarkable application potentials in mineral processing wastewater treatment compared to traditional Fenton reaction,reducing oxidant consumption and increasing organic carbon recovery.This study enhances development of resource-efficient Fenton-like oxidation technologies for mineral processing wastewater treatment.
基金sponsored by the National Natural Science Foundation of China(62473154,62473155,62473156)the Natural Science Foundation of Shanghai(19ZR1473200)+1 种基金Shanghai Oriental Talents Program Youth Project(QNKJ2024034)Shanghai Chenguang Project(21CGA37).
摘要With the complexity and intelligence of the industrial process,the identificationof faults in the actual process plays a crucial role in ensuring production safety.The traditional fault identificationstrategies have the problem that similar characterized faults are unable to be accurately identified.Motivated by the limitations,a novel sample-optimized adaptive perceptual enhanced graph neural network(SOAPEGNN)for large-scale process fault identificationis proposed.Initially,process mechanism knowledge and process data correlation are injected into the modeling approach through graph neural networks,and the transmission of information based on the enhanced attention mechanism is introduced to describe the quantitative relationships between process variables at a fine-grainedlevel based on the adaptive perception strategy.Subsequently,to achieve better intra-class compactness and inter-class separability in feature representation,our designed sample-optimized feature processing strategy(SOFPS)is applied.Furthermore,to enhance the robustness and generalization capability of the model during training,a label smoothing regularization(LSR)strategy is incorporated.This approach effectively mitigates the risk of overfittingby introducing a degree of uncertainty into the label space,thereby encouraging the model to learn more discriminative and stable features.Ultimately,the efficacy and superiority of the SOAP-EGNN algorithm are thoroughly validated through comprehensive simulation experiments conducted on the Tennessee Eastman process(TEP).
基金supported by the National Key Research and Development Program for Young Scientists,China(No.2023YFB3508400)the National Natural Science Foundation of China(Nos.51871005,51931007)+1 种基金the Key Program of Science and Technology Development Project of Beijing Municipal Education Commission of China(No.KZ202010005009)the Program of Top Disciplines Construction in Beijing,China(No.PXM2019_014204_500031)。
摘要To improve the overall magnetic properties of Sm(CoFeCuZr)zsintered magnets,a dual-alloy sintering process that involves mixing high-iron,low-copper powders with low-iron,high-copper powders was systematically investigated.The results demonstrate that this method significantly improves the Cu-lean phenomenon at the grain boundaries,achieves multiscale uniform microstructures,greatly enhances the pinning field strength,and ultimately produces a high-performance dual-alloy magnet with a maximum energy product((BH)max)exceeding 240 kJ/m3and an intrinsic coercivity(Hcj)exceeding 2400 kA/m.In particular,when 35 wt.%of low-iron,high-copper alloy powder is incorporated,the dual-alloy magnet achieves a remanence of 1.13 T,Hcjof 2691.2 kA/m and(BH)maxof 248 kJ/m3.To evaluate the overall magnetic performance,the sum of Hcj(in kA/m)and(BH)max(in kJ/m3)is used as a combined parameter,yielding a value of 2939.2.Compared with single-alloy magnets of the same composition,the dual-alloy sintering process yields magnets with a more uniform elemental distribution and superior magnetic properties.