Carbon Capture,Utilization,and Storage(CCUS)technology has gained widespread attention in recent years as a critical strategy to combat global climate change,particularly in achieving carbon neutrality goals.The Guang...Carbon Capture,Utilization,and Storage(CCUS)technology has gained widespread attention in recent years as a critical strategy to combat global climate change,particularly in achieving carbon neutrality goals.The Guangdong-Hong Kong-Macao Greater Bay Area(GBA),as one of China's most economically active regions,serves as a key engine for economic growth while also facing considerable carbon emission challenges.This study analyzes the industrial emission volume and geographical distribution of key emitting enterprises in the GBA,summarizes their technological processes and main carbonemitting equipment,and provides scientific support for precise mitigation policies and low-carbon development.Based on data from 176 key emitting enterprises,the study reveals that Guangzhou and Dongguan host the largest number of such enterprises.Carbon emissions are primarily concentrated in the power sector,dominated by coal-and gas-fired power units,characterized by significant spatial dispersion and uneven distribution.Beyond the power sector,the paper industry has a high number of enterprises but lower emissions.Key facilities such as boilers,cogeneration systems,and production lines are predominantly located near tributaries rivers in Dongguan and Jiangmen.The building materials sector,primarily cement production,ranks as the second-largest emitter,with hightemperature kilns and grinding equipment,particularly rotary kilns and glass furnaces,as the main sources.The petrochemical and chemical sectors have fewer enterprises and lower emissions in the GBA,mainly located in suburban industrial clusters.Carbon emissions in the GBA exhibit distinct industry concentration and geographical distribution disparities.This study provides crucial data and theoretical insights for the development of targeted emission reduction strategies,optimization of source-sink matching,and the advancement of CCUS technologies in the region,particularly from the GBA to the northern South China Sea.展开更多
Traditional targeted analyses often overlook unknown or emerging contaminants,highlighting the significance of nontarget and suspect screening approaches.A novel and high-sensitivity methodology for nontarget analysis...Traditional targeted analyses often overlook unknown or emerging contaminants,highlighting the significance of nontarget and suspect screening approaches.A novel and high-sensitivity methodology for nontarget analysis of organic pollutants in human serum was newly-developed based on gas chromatography coupled with quadrupole time-of-flight high-resolution mass spectrometry.The extraction protocol employing an acetonitrile-ethyl acetate(9:1,V:V)mixture significantly improved the extraction efficiency while minimizing matrix effect.A hybridized analytical strategy integrating nontarget and suspect screening was developed to achieve comprehensive identification and classification of pollutants,employing the National Institute of Standards and Technology(NIST)20 library and Agilent Technologies Personal Compound Database and Library(PCDL).This approach successfully characterized 273 organic contaminants spanning 12 categories,including polycyclic aromatic hydrocarbons(PAHs)and their derivatives,esters,and phenolic compounds in human serum,with a significant increase in detection specificity compared to conventional workflows.The methodology used serum samples of the workers from coking industry,revealing widespread contamination dominated by PAHs and PAH derivatives.Among the target analytes,three were identified solely by NIST and six solely by PCDL,indicating the complementary benefits of combining these different databases.Notably,this work reported the first confirmed detection of 2-naphthalenamine in human serum.This optimized approach demonstrates enhanced sensitivity and reliability in serum analysis,advancing biomonitoring capabilities and providing a deep understanding of human exposure to environmental pollutants.展开更多
A proper non-landslide sample selection strategy can improve landslide susceptibility prediction(LSP)accuracy.However,there may be uncertainties regarding the compatibility between different selection strategies and m...A proper non-landslide sample selection strategy can improve landslide susceptibility prediction(LSP)accuracy.However,there may be uncertainties regarding the compatibility between different selection strategies and machine learning models,as well as in the extent of LSP performance enhancement after their coupling.To overcome these uncertainties,this study takes Wuning county of China as a case area,collecting 24 conditioning factors and 379 landslides data.Four non-landslide sample selection strategies,namely random selection,low-slope,buffer zone,and semi-supervised strategies,are then combined with landslide samples in a 1:1 ratio to serve as input variables for constructing LSP models using support vector machine(SVM),logistic regression(LR),random forest(RF)and extreme gradient boosting(XGBoost).Finally,the uncertainty of semi-supervised machine learning coupled models with a 1:2 ratio of landslide to non-landslide samples is analyzed and compared.The results show that:(1)The semi-supervised and low-slope strategies demonstrate higher prediction accuracy compared to the buffer zone and random selection strategies.Moreover,the RF coupled models are the most reliable,followed by the XGBoost,SVM,and LR coupled models;(2)Compared to a 1:1 ratio,a 1:2 ratio of landslide to non-landslide samples significantly improves prediction accuracy,suggesting that appropriately increasing the proportion of non-landslide samples helps to mitigate overfitting and enhance the identification of landslide samples;and(3)LSP is more sensitive to non-landslide sample selection strategies than to the choice of machine learning models.In conclusion,prioritizing reliable non-landslide samples is crucial for improving accuracy of LSP.展开更多
Perfluorooctanoic acid(PFOA)is a ubiquitous persistent organic pollutant.Hence,developing effective strategies for its fast and efficient detection in environmental samples is imperative for ecological and health safe...Perfluorooctanoic acid(PFOA)is a ubiquitous persistent organic pollutant.Hence,developing effective strategies for its fast and efficient detection in environmental samples is imperative for ecological and health safety.Herein,red-emissive carbon dots(R-CDs)were innovatively fabricated and employed to construct a novel eco-friendly fluorescence and colorimetric dual-mode probe for the effective determination of PFOA.The R-CDs were sourced from meso‑tetra(4-carboxyphenyl)porphine,ethanolamine,and oxalic acid via a facile hydrothermal method.The fluorescent intensity of the R-CDs at 652 nm and the absorbance at 415 nm decreased gradually with increasing concentration of PFOA.The experimental results demonstrated the probe exhibited good linearity across PFOA concentration ranges of 1–100 ng/mL,100–900 ng/mL,and 1000–4000 ng/mL based on fluorescence quenching attributable to the static quenching.Additionally,the probe achieved high sensitivity with a detection limit as low as 0.0012 ng/mL.On the other hand,the probe could detect PFOA in the range of 1000–7000 ng/mL with a detection limit of 54.9 ng/mL according to colorimetric principle.This probe exhibited excellent reliability and satisfactory recoveries when analyzing the trace PFOA in actual water and soil samples.The proposed probe provided a simple,rapid,economical,and environmentally friendly platform for effectively,selectively,and sensitively detecting PFOA in environmental samples.展开更多
Successful ex situ conservation of plant populations requires a high degree of genetic representativeness.However,spatially biased sampling in ex situ conservation efforts may fail to capture all wild genetic clusters...Successful ex situ conservation of plant populations requires a high degree of genetic representativeness.However,spatially biased sampling in ex situ conservation efforts may fail to capture all wild genetic clusters for species with range-wide genetic structure.To investigate the extent of spatially biased sampling in living collections and the coverage of wild genetic clusters in plant populations under ex situ conservation worldwide,we combined a global synthesis of ex situ conservation efforts with a case study of an endangered riparian plant species,Myricaria laxiflora.Our analysis of ex situ conservation worldwide revealed that the majority(82.6%)of ex situ populations fail to cover all wild genetic clusters,largely due to spatially biased sampling with low geographic coverage.Our case study of M.laxiflora showed that genetic diversity differed between the ex situ and upstream populations,while it was comparable between ex situ populations and other wild populations.However,current ex situ populations did not cover all wild genetic clusters,as the upstream genetic cluster was previously uncollected.Our study suggests that the failure to cover all wild genetic clusters in ex situ populations is a widespread issue,and ex situ populations with high genetic diversity can also fail to cover all wild genetic clusters.In future ex situ conservation programs,both the importance of high genetic diversity and the high coverage of wild genetic clusters should be prioritized.展开更多
In-situ monitoring methods and deep learning models are increasingly being used for the quality assessment of parts fabricated using laser powder bed fusion to overcome the limitations of poor process repeatability.Ho...In-situ monitoring methods and deep learning models are increasingly being used for the quality assessment of parts fabricated using laser powder bed fusion to overcome the limitations of poor process repeatability.However,the massive data collection required for part-quality monitoring results in high transmission loads and storage costs.To address this problem,this study utilized the compressed sensing theory to acquire compressed photodiode signals.These signals were then used to train and test convolutional neural networks(CNN)to identify the lack-of-fusion,normal,and keyhole modes.At a compressive-sampling rate of 25%,the classification accuracy decreased from 93.1%(raw signals)to 79.3%.However,increasing the compression rate from 25%to 90%did not significantly decrease the classification accuracy.The linear mapping of the raw signal via a Gaussian measurement matrix causes coordinate information folding,thereby impairing the representation of latent features.Therefore,Gaussian process modeling was adopted for the features extracted using a pretrained CNN to mitigate the temporal information collapse and allow the compressed signals to achieve an accuracy comparable to that of the raw data.Furthermore,the sparsity and rank complexity of the melt-pool radiation signals were evaluated using sparse representation and principal component analysis.展开更多
With the rapid advancement of quantum computing,traditional security protocols based on classical encryption algorithms are increasingly vulnerable to potential quantum attacks.The current IPsec protocol,which relies ...With the rapid advancement of quantum computing,traditional security protocols based on classical encryption algorithms are increasingly vulnerable to potential quantum attacks.The current IPsec protocol,which relies on classical cryptographic methods,is insufficient to withstand such threats,thereby compromising the security of long-term data transmission.To address this issue,we propose integrating quantum key distribution(QKD)into the internet protocol security(IPsec)protocol,thereby enhancing its resilience against quantum computing attacks.Here,two schemes that merge QKDgenerated keys with classical cryptographic keys are designed to enhance both security and stability.Furthermore,we conduct a comprehensive evaluation of the performance of various QKD protocols implemented with the scheme,along with an assessment of its overall efficacy across a topological network configuration.This approach not only ensures secure data transmission in the era of quantum computing but also highlights the potential application value of integrating QKD with IPsec,providing valuable insights for the design and implementation of future quantum-secure communication systems.展开更多
Glycosylation-omics has emerged as a prominent field for early detection and diagnosis by identifying alterations in glycosylation patterns linked to cancer.In the realm of clinical multi-glycosylation-omics applicati...Glycosylation-omics has emerged as a prominent field for early detection and diagnosis by identifying alterations in glycosylation patterns linked to cancer.In the realm of clinical multi-glycosylation-omics applications,there is a critical need for robust,efficient,and cost-effective preprocessing methodologies capable of handling large sample cohorts.To bridge this gap,we introduce the GlycoPro platform,an innovative solution designed to overcome the limitations of existing analysis methods.Tailored for multi-glycosylation-omics sample preprocessing,GlycoPro refines existing workflows by seamlessly integrating steps including protein extraction,desalting,digestion,derivatization,and enrichment.The GlycoPro platform employs a 96-well plate format,enabling the efficient enrichment or desalting of up to 384 samples in a single day.This capability represents a significant increase in throughput,meeting the demands of large-scale clinical sample preprocessing for mass spectrometry analysis.The GlycoPro platform was used to successfully enrich serum N-glycans from breast cancer patients,revealing unique glycomic signatures that distinguish malignant from benign conditions.We have developed a robust Nglycan biomarker panel,demonstrating a sensitivity of 88.24%and a specificity of 78.95%in diagnostics.展开更多
The overuse and improper disposal of tetracyclines raise significant environmental and public health concerns due to their persistent ecotoxicological effects.However,there is still a lack of simple,readily available,...The overuse and improper disposal of tetracyclines raise significant environmental and public health concerns due to their persistent ecotoxicological effects.However,there is still a lack of simple,readily available,and effective method for simultaneously detecting multiple tetracyclines.Herein,we present a simple fluorescent sensor array for the detection and identification of multiple tetracyclines(including tetracycline,oxytetracycline,chlortetracycline,and doxycycline)based on host-guest recognitions between albumin(host)and tetracycline(guest).Upon entering the hydrophobic cavity of albumin,tetracycline exhibits a significant enhancement in its intrinsic fluorescence.The differential binding affinity of two albumins to four tetracyclines resulted in different fluorescent responses,creating distinct fluorescence patterns for each tetracycline.With the assistance of machine learning technique,including linear discriminant analysis(LDA)and hierarchical cluster analysis(HCA),this sensor array demonstrated the significant discrimination and classification capabilities for four common tetracyclines and their mixtures with 100%accuracy.Additionally,the array has been successfully applied to differentiate tetracyclines in real food samples.The spiked antibiotics in water sample were determined with a satisfactory recovery of 96.33%-106.5%.This work offers a simple but promising method for differentiating tetracycline antibiotics and presents a versatile strategy for sensor array design.展开更多
Soil microbial-metabolite interactions influence crop productivity,yet their responses to long-term nutrient management in legume systems warrant further investigation.This study examined how fertilization and Bradyrh...Soil microbial-metabolite interactions influence crop productivity,yet their responses to long-term nutrient management in legume systems warrant further investigation.This study examined how fertilization and Bradyrhizobium inoculation reshape soybean rhizosphere fungal-metabolite networks to improve soil health.Through a decade-long field trial utilizing internal transcribed spacer(ITS) sequencing and liquid chromatography-mass spectrometry(LC-MS) metabolomics,four treatments were evaluated:no fertilizer application(CK);phosphorus and potassium fertilization(PK);PK chemical fertilizers combined with urea(PK+N);PK fertilization with Bradyrhizobium japonicum 5821 inoculation(PK+R).Results indicated that nitrogen fertilization increased fungal diversity at maturity and enhanced co-occurrence network complexity(displaying the highest node and edge counts),while Bradyrhizobium inoculation promoted stochastic assembly.Soil fungi exhibited notable correlations with 3-hydroxymethylantipyrine,chrysophanol,3,7-dihydroxyflavone and triethylamine.Metabolite profiling revealed nitrogen suppression of stress-resistant flavonoids(3-hydroxymethylantipyrine,chrysophanol,3,7-dihydroxyflavone),whereas Bradyrhizobium enhanced these key metabolites.KEGG enrichment identified tryptophan and caffeine metabolism as central during flowering-podding stage,coordinating nitrogen assimilation and defense responses.Additionally,the key metabolites correlated significantly with soil total nitrogen,organic matter,and available nitrogen.These findings reveal that Bradyrhizobium acts synergistically with fertilization to activate fungal-driven metabolic pathways,offering a microbiome-based approach to enhance nitrogen efficiency and reduce agrochemical dependency in soybean systems.展开更多
Accurate modeling of carbon sequestration by forests requires scaling wood formation processes from trees to the landscape.The quantification of growth and carbon dynamics requires deep knowledge of the variability in...Accurate modeling of carbon sequestration by forests requires scaling wood formation processes from trees to the landscape.The quantification of growth and carbon dynamics requires deep knowledge of the variability in xylem phenology among individuals.This study presents a comprehensive assessment of seasonal and individual variability in xylem phenology based on more than 800 balsam firs(Abies balsamea(L.)Mill.)monitored weekly across 33 plots from 2018 to 2022 in Montmorency Forest,Quebec,Canada.Wood microcores were collected from April to October to quantify the timings of cambial activity and xylem development on anatomical sections observed at high magnification under the microscope.The first enlarging cells appeared between late May and early June(day of the year(DOY)153-167),and cell-wall thickening ended in late August(DOY 223-238),resulting in a growing season of 63-79 days.Xylem production ranged from 27.4 to 47.9 radial cells.While the onset of xylogenesis was well synchronized among individuals,within 2 weeks,the cessation of growth showed a greater variability,reaching up to 3 weeks.This autumnal variability was positively correlated with wood production,as higher cambial activity increases the accumulation of xylem cells to be differentiated.Our findings provide empirical evidence that individual variability in growth cessation reflects the underlying heterogeneity in cambial activity among trees of the same stand.Our results demonstrate the role of xylem phenology,especially during the autumn,in shaping forest growth.The assessment of both seasonal and individual variability in phenology is an essential step to improve the representation of autumn processes in forest carbon models,which can help to reduce the uncertainty in predictions of boreal forest growth under current or future climate scenarios.展开更多
宝鸡市滑坡灾害频发,但当前该区域滑坡编录数据样本较少,同时若仅采用滑坡点样本训练模型会导致模型的空间代表性不足,从而制约对该区域滑坡易发性评价的精度。针对此,结合卷积神经网络模型(convolutional neural net‐work,CNN)的局部...宝鸡市滑坡灾害频发,但当前该区域滑坡编录数据样本较少,同时若仅采用滑坡点样本训练模型会导致模型的空间代表性不足,从而制约对该区域滑坡易发性评价的精度。针对此,结合卷积神经网络模型(convolutional neural net‐work,CNN)的局部特征提取优势和注意力机制Transformer的全局建模能力,提出一种融合Transformer与CNN的正样本缓冲滑坡易发性评价模型。依据滑坡规模设置90~130 m动态缓冲区扩展正样本,并综合考虑地形地貌、地质条件、水文气象和人类工程等选取13类滑坡影响因子,通过多重共线性分析后构建了滑坡评价体系。研究结果显示,采用缓冲区将随机森林、CNN、Transformer、Transformer-CNN模型四者的ROC曲线下的面积(area under the curve,AUC)从0.834、0.852、0.847、0.875分别提升至0.883、0.913、0.926、0.959。此外,Transformer-CNN相较CNN、Transformer,未缓冲时AUC分别从0.852、0.847提升至0.875,进行缓冲时分别从0.913、0.926提升至0.959;基于夏普利加性解释算法可解释性分析进一步揭示出岩性、年降雨、坡向三类因子对滑坡易发性预测贡献度最大,贡献度分别达0.55、0.47、0.43,且三者交互效应显著,为锁定区域滑坡高易发区提供了可量化的依据。展开更多
Seismic amplitude variation with offset(AVO)inversion is a cornerstone of oil and gas reservoir prediction,enabling the estimation of subsurface elastic parameters and characterization of stratigraphic interfaces.Howe...Seismic amplitude variation with offset(AVO)inversion is a cornerstone of oil and gas reservoir prediction,enabling the estimation of subsurface elastic parameters and characterization of stratigraphic interfaces.However,balancing inversion accuracy and computational efficiency remains a critical challenge.To address this,we propose a novel probabilistic AVO inversion framework integrating three key innovations.First,we derive a high-precision quadratic approximation for compressional(P-wave)reflectivity by retaining first-and second-order terms from the exact Zoeppritz equations through a perturbation strategy.This approach significantly enhances accuracy compared to conventional linear approximations,particularly in reflecting the true amplitude variation at large angles.Subsequently,to improve lateral continuity and stratigraphic resolution,we introduce an instantaneous phase constraint derived via the Hilbert transform.This constraint leverages phase sensitivity to seismic waveform coherence,ensuring geologically consistent interface characterization during stochastic inversion.Furthermore,we develop a hybrid Markov Chain Monte Carlo(MCMC)algorithm combining adaptive Gibbs sampling with the independent doubly adaptive rejection Metropolis sampling(IA2RMS)method.This framework efficiently samples high-dimensional posterior probability density functions(PDFs)of elastic pa rameters:Gibbs sampling gene rates adaptive proposal distributions,while IA2RMS accele rates Markov chain convergence through location-and scale-adjustable proposals.Numerical experiments and field seismic data demonstrate the robustness and feasibility of the proposed probabilistic AVO inversion method.展开更多
Artificial Intelligence(AI)in healthcare enables predicting diabetes using data-driven methods instead of the traditional ways of screening the disease,which include hemoglobin A1c(HbA1c),oral glucose tolerance test(O...Artificial Intelligence(AI)in healthcare enables predicting diabetes using data-driven methods instead of the traditional ways of screening the disease,which include hemoglobin A1c(HbA1c),oral glucose tolerance test(OGTT),and fasting plasma glucose(FPG)screening techniques,which are invasive and limited in scale.Machine learning(ML)and deep neural network(DNN)models that use large datasets to learn the complex,nonlinear feature interactions,but the conventional ML algorithms are data sensitive and often show unstable predictive accuracy.Conversely,DNN models are more robust,though the ability to reach a high accuracy rate consistently on heterogeneous datasets is still an open challenge.For predicting diabetes,this work proposed a hybrid DNN approach by integrating a bidirectional long short-term memory(BiLSTM)network with a bidirectional gated recurrent unit(BiGRU).A robust DL model,developed by combining various datasets with weighted coefficients,dense operations in the connection of deep layers,and the output aggregation using batch normalization and dropout functions to avoid overfitting.The goal of this hybrid model is better generalization and consistency among various datasets,which facilitates the effective management and early intervention.The proposed DNN model exhibits an excellent predictive performance as compared to the state-of-the-art and baseline ML and DNN models for diabetes prediction tasks.The robust performance indicates the possible usefulness of DL-based models in the development of disease prediction in healthcare and other areas that demand high-quality analytics.展开更多
Herein,ratiometric fluorescence-based carbon dots(N-CDs)with blue emission were prepared by using simple one-step hydrothermal methods from benzimidazole and L-tryptophan as precursors.Dual emission peaks were observe...Herein,ratiometric fluorescence-based carbon dots(N-CDs)with blue emission were prepared by using simple one-step hydrothermal methods from benzimidazole and L-tryptophan as precursors.Dual emission peaks were observed at 356 and 442 nm under the excitation wavelength of 303 nm.Upon addition of sulfide ions(S2-),the fluorescence intensity at 442 nm decreased significantly,while that at 356 nm increased.The F442/F356 intensity ratio(where F356 and F442 refer to the fluorescence intensity at 356 and 442 nm,respectively)exhibited a linear relationship with the concentration of S2-(0-60.0μmol·L-1),and the detection limit was determined to be 0.076μmol·L-1.The fluorescence detection mechanism was ascribed to the static quenching effect.Furthermore,this fluorescence probe was successfully used for the determination of S2-in real samples with satisfactory recoveries.Finally,the analytical greenness metric for sample preparation(AGREEprep)and blue applicability grade index(BAGI)tools indicated the high sustainability of this platform.展开更多
Quantum key distribution(QKD)has been widely deployed in practical applications after decades of development.However,the QKD system is easily affected by the external environment,especially free-space QKD.In this text...Quantum key distribution(QKD)has been widely deployed in practical applications after decades of development.However,the QKD system is easily affected by the external environment,especially free-space QKD.In this text,we examine two scenarios of free-space QKD in urban environments:satellite to ground and intercity.For satellite to ground QKD,the effects of stray light are analyzed.For intercity link,we discuss the influence of sea salt particles in coastal cities,and insoluble and soot particles in inland cities.Our findings indicate that using a telescope with a smaller field of view(FOV)and larger aperture diameters in satellite-to-ground QKD can effectively reduce errors induced by stray light.However,the diameter cannot be increased infinitely,when exceeding 0.8 m,the number of stray photons entering receiver rises rapidly and the quantum bits error rate(QBER)shows no significant reduction.For intercity QKD,the strength of extinction varies with relative humidity and aerosol particle radius,consequently altering channel transmittance.We investigate the impact of sea salt,insoluble particles,and soot on the key rate,finding that under the number density N=106m-3,sea salt exhibits the strongest impacts on key rate,especially when radius exceed 2.5μm.The impacts of insoluble particles are weaker and soot is the weakest,which can be ignored until N reaches 109m-3.For larger particle density,we can get higher key rate and further transmission distances in a soot-dominated environment.Our work could provide a valuable reference for the practical implementation of QKD in urban atmospheres.展开更多
Physical layer security(PLS)has become a critical technique for the rapidly expanding communication network in the postquantum era,supporting superior secure communication rates with lower deployment cost.Typical PLS ...Physical layer security(PLS)has become a critical technique for the rapidly expanding communication network in the postquantum era,supporting superior secure communication rates with lower deployment cost.Typical PLS architecture follows the“key distribution before encrypted communication”paradigm,which causes redundant system structure and potential security issues.We propose an intrinsic physical layer secure communication architecture aided by a joint secure key distribution technique in this article.The architecture utilizes random time-varying polarization evolution induced by the fiber channel as the entropy source and estimated bit error rate information as the medium to implement an intrinsic key distribution scheme without requiring additional channels and complex devices.We realize simultaneous physical layer encrypted transmission and error-free joint secure key distribution(SKD)based on this architecture.The experimental demonstration verifies the feasibility of the scheme.We believe the highly integrated secure communication architecture with multiple guaranteed security measures may not only provide a feasible,low-cost solution for the deployment of the SKD system in a variety of communication scenarios,but also propose a“key distribution within encrypted communication”paradigm for future PLS solutions.展开更多
基金supported by the National Natural Science Foundation of China(52304098,52106092,42376215,52474105)Shenzhen Science and Technology Program(JCYJ20220818095605012,JCYJ20220530113011027)+5 种基金Guangdong Basic and Applied Basic Research Foundation(2022A1515110338,2023A1515012316,2023A1515012761,2025A1515010748)Research Team Cultivation Program of Shenzhen University(2023QNT004)Shenzhen Key Laboratory of Natural Gas Hydrates(ZDSYS20200421111201738)the General Research Fund(No.12616222)Early Career Scheme(No.22611624)of Hong Kong Research Grants CouncilMajor Science and Technology Infrastructure Project of Material Genome Big–science Facilities Platform supported by the Municipal Development and Reform Commission of Shenzhen。
摘要Carbon Capture,Utilization,and Storage(CCUS)technology has gained widespread attention in recent years as a critical strategy to combat global climate change,particularly in achieving carbon neutrality goals.The Guangdong-Hong Kong-Macao Greater Bay Area(GBA),as one of China's most economically active regions,serves as a key engine for economic growth while also facing considerable carbon emission challenges.This study analyzes the industrial emission volume and geographical distribution of key emitting enterprises in the GBA,summarizes their technological processes and main carbonemitting equipment,and provides scientific support for precise mitigation policies and low-carbon development.Based on data from 176 key emitting enterprises,the study reveals that Guangzhou and Dongguan host the largest number of such enterprises.Carbon emissions are primarily concentrated in the power sector,dominated by coal-and gas-fired power units,characterized by significant spatial dispersion and uneven distribution.Beyond the power sector,the paper industry has a high number of enterprises but lower emissions.Key facilities such as boilers,cogeneration systems,and production lines are predominantly located near tributaries rivers in Dongguan and Jiangmen.The building materials sector,primarily cement production,ranks as the second-largest emitter,with hightemperature kilns and grinding equipment,particularly rotary kilns and glass furnaces,as the main sources.The petrochemical and chemical sectors have fewer enterprises and lower emissions in the GBA,mainly located in suburban industrial clusters.Carbon emissions in the GBA exhibit distinct industry concentration and geographical distribution disparities.This study provides crucial data and theoretical insights for the development of targeted emission reduction strategies,optimization of source-sink matching,and the advancement of CCUS technologies in the region,particularly from the GBA to the northern South China Sea.
基金supported by the National Key Research and Development Project(Nos.2023YFC3905102 and 2024YFC3713201)the National Natural Science Foundation of China(Nos.42207485 and 42407567).
摘要Traditional targeted analyses often overlook unknown or emerging contaminants,highlighting the significance of nontarget and suspect screening approaches.A novel and high-sensitivity methodology for nontarget analysis of organic pollutants in human serum was newly-developed based on gas chromatography coupled with quadrupole time-of-flight high-resolution mass spectrometry.The extraction protocol employing an acetonitrile-ethyl acetate(9:1,V:V)mixture significantly improved the extraction efficiency while minimizing matrix effect.A hybridized analytical strategy integrating nontarget and suspect screening was developed to achieve comprehensive identification and classification of pollutants,employing the National Institute of Standards and Technology(NIST)20 library and Agilent Technologies Personal Compound Database and Library(PCDL).This approach successfully characterized 273 organic contaminants spanning 12 categories,including polycyclic aromatic hydrocarbons(PAHs)and their derivatives,esters,and phenolic compounds in human serum,with a significant increase in detection specificity compared to conventional workflows.The methodology used serum samples of the workers from coking industry,revealing widespread contamination dominated by PAHs and PAH derivatives.Among the target analytes,three were identified solely by NIST and six solely by PCDL,indicating the complementary benefits of combining these different databases.Notably,this work reported the first confirmed detection of 2-naphthalenamine in human serum.This optimized approach demonstrates enhanced sensitivity and reliability in serum analysis,advancing biomonitoring capabilities and providing a deep understanding of human exposure to environmental pollutants.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.42202278,42407241)Natural Science Foundation of Jiangxi Province(Grant No.20242BAB20238).
摘要A proper non-landslide sample selection strategy can improve landslide susceptibility prediction(LSP)accuracy.However,there may be uncertainties regarding the compatibility between different selection strategies and machine learning models,as well as in the extent of LSP performance enhancement after their coupling.To overcome these uncertainties,this study takes Wuning county of China as a case area,collecting 24 conditioning factors and 379 landslides data.Four non-landslide sample selection strategies,namely random selection,low-slope,buffer zone,and semi-supervised strategies,are then combined with landslide samples in a 1:1 ratio to serve as input variables for constructing LSP models using support vector machine(SVM),logistic regression(LR),random forest(RF)and extreme gradient boosting(XGBoost).Finally,the uncertainty of semi-supervised machine learning coupled models with a 1:2 ratio of landslide to non-landslide samples is analyzed and compared.The results show that:(1)The semi-supervised and low-slope strategies demonstrate higher prediction accuracy compared to the buffer zone and random selection strategies.Moreover,the RF coupled models are the most reliable,followed by the XGBoost,SVM,and LR coupled models;(2)Compared to a 1:1 ratio,a 1:2 ratio of landslide to non-landslide samples significantly improves prediction accuracy,suggesting that appropriately increasing the proportion of non-landslide samples helps to mitigate overfitting and enhance the identification of landslide samples;and(3)LSP is more sensitive to non-landslide sample selection strategies than to the choice of machine learning models.In conclusion,prioritizing reliable non-landslide samples is crucial for improving accuracy of LSP.
基金supported by the National Natural Science Foundation of China(Nos.22106039 and 21976211)the Program for Innovative Research Team in Science and Technology in the University of Henan Province(No.20IRTSTHN011).
摘要Perfluorooctanoic acid(PFOA)is a ubiquitous persistent organic pollutant.Hence,developing effective strategies for its fast and efficient detection in environmental samples is imperative for ecological and health safety.Herein,red-emissive carbon dots(R-CDs)were innovatively fabricated and employed to construct a novel eco-friendly fluorescence and colorimetric dual-mode probe for the effective determination of PFOA.The R-CDs were sourced from meso‑tetra(4-carboxyphenyl)porphine,ethanolamine,and oxalic acid via a facile hydrothermal method.The fluorescent intensity of the R-CDs at 652 nm and the absorbance at 415 nm decreased gradually with increasing concentration of PFOA.The experimental results demonstrated the probe exhibited good linearity across PFOA concentration ranges of 1–100 ng/mL,100–900 ng/mL,and 1000–4000 ng/mL based on fluorescence quenching attributable to the static quenching.Additionally,the probe achieved high sensitivity with a detection limit as low as 0.0012 ng/mL.On the other hand,the probe could detect PFOA in the range of 1000–7000 ng/mL with a detection limit of 54.9 ng/mL according to colorimetric principle.This probe exhibited excellent reliability and satisfactory recoveries when analyzing the trace PFOA in actual water and soil samples.The proposed probe provided a simple,rapid,economical,and environmentally friendly platform for effectively,selectively,and sensitively detecting PFOA in environmental samples.
基金supported by National Key Research and Development Program of China(2024YFF1307400)Hubei Provincial Natural Science Foundation and Three Gorges Innovation Development Joint Fund(Grant No.2023AFD195)China Three Gorges Corporation(NBZZ202300130).
摘要Successful ex situ conservation of plant populations requires a high degree of genetic representativeness.However,spatially biased sampling in ex situ conservation efforts may fail to capture all wild genetic clusters for species with range-wide genetic structure.To investigate the extent of spatially biased sampling in living collections and the coverage of wild genetic clusters in plant populations under ex situ conservation worldwide,we combined a global synthesis of ex situ conservation efforts with a case study of an endangered riparian plant species,Myricaria laxiflora.Our analysis of ex situ conservation worldwide revealed that the majority(82.6%)of ex situ populations fail to cover all wild genetic clusters,largely due to spatially biased sampling with low geographic coverage.Our case study of M.laxiflora showed that genetic diversity differed between the ex situ and upstream populations,while it was comparable between ex situ populations and other wild populations.However,current ex situ populations did not cover all wild genetic clusters,as the upstream genetic cluster was previously uncollected.Our study suggests that the failure to cover all wild genetic clusters in ex situ populations is a widespread issue,and ex situ populations with high genetic diversity can also fail to cover all wild genetic clusters.In future ex situ conservation programs,both the importance of high genetic diversity and the high coverage of wild genetic clusters should be prioritized.
基金supported by National Natural Science Foundation of China(Grant No.52475350)National Key R&D Program of China(Grant Nos.2022YFF0606000,2023YFB4606702)+3 种基金National Natural Science Foundation of China(Grant No.U2001218)Guangdong Basic and Applied Basic Research Foundation(Grant No.2022B1515120066)Fundamental Research Funds for Central Universities(Grant No.2024ZYGXZR023)National Natural Science Foundation of China(Grant No.51875215).
摘要In-situ monitoring methods and deep learning models are increasingly being used for the quality assessment of parts fabricated using laser powder bed fusion to overcome the limitations of poor process repeatability.However,the massive data collection required for part-quality monitoring results in high transmission loads and storage costs.To address this problem,this study utilized the compressed sensing theory to acquire compressed photodiode signals.These signals were then used to train and test convolutional neural networks(CNN)to identify the lack-of-fusion,normal,and keyhole modes.At a compressive-sampling rate of 25%,the classification accuracy decreased from 93.1%(raw signals)to 79.3%.However,increasing the compression rate from 25%to 90%did not significantly decrease the classification accuracy.The linear mapping of the raw signal via a Gaussian measurement matrix causes coordinate information folding,thereby impairing the representation of latent features.Therefore,Gaussian process modeling was adopted for the features extracted using a pretrained CNN to mitigate the temporal information collapse and allow the compressed signals to achieve an accuracy comparable to that of the raw data.Furthermore,the sparsity and rank complexity of the melt-pool radiation signals were evaluated using sparse representation and principal component analysis.
基金supported by the Jiangsu Provincial Key R&D Program for Industrialization Prospects and Key Core Technology Project(Grant No.BE2022071)the National Natural Science Foundation of China(NSFC)(Grant Nos.62471248,62201276,and 12074194)。
摘要With the rapid advancement of quantum computing,traditional security protocols based on classical encryption algorithms are increasingly vulnerable to potential quantum attacks.The current IPsec protocol,which relies on classical cryptographic methods,is insufficient to withstand such threats,thereby compromising the security of long-term data transmission.To address this issue,we propose integrating quantum key distribution(QKD)into the internet protocol security(IPsec)protocol,thereby enhancing its resilience against quantum computing attacks.Here,two schemes that merge QKDgenerated keys with classical cryptographic keys are designed to enhance both security and stability.Furthermore,we conduct a comprehensive evaluation of the performance of various QKD protocols implemented with the scheme,along with an assessment of its overall efficacy across a topological network configuration.This approach not only ensures secure data transmission in the era of quantum computing but also highlights the potential application value of integrating QKD with IPsec,providing valuable insights for the design and implementation of future quantum-secure communication systems.
基金supported by the National Key Research and Development Program of China(2024YFA1306301)the National Natural Science Foundation of China(NSFC+3 种基金22174021 and 22434001)Shanghai Municipal Science and Technology Major Project(2023SHZDZX02)the Greater Bay Area Institute of Precision Medicine(GuangzhouIPM2021C005)。
摘要Glycosylation-omics has emerged as a prominent field for early detection and diagnosis by identifying alterations in glycosylation patterns linked to cancer.In the realm of clinical multi-glycosylation-omics applications,there is a critical need for robust,efficient,and cost-effective preprocessing methodologies capable of handling large sample cohorts.To bridge this gap,we introduce the GlycoPro platform,an innovative solution designed to overcome the limitations of existing analysis methods.Tailored for multi-glycosylation-omics sample preprocessing,GlycoPro refines existing workflows by seamlessly integrating steps including protein extraction,desalting,digestion,derivatization,and enrichment.The GlycoPro platform employs a 96-well plate format,enabling the efficient enrichment or desalting of up to 384 samples in a single day.This capability represents a significant increase in throughput,meeting the demands of large-scale clinical sample preprocessing for mass spectrometry analysis.The GlycoPro platform was used to successfully enrich serum N-glycans from breast cancer patients,revealing unique glycomic signatures that distinguish malignant from benign conditions.We have developed a robust Nglycan biomarker panel,demonstrating a sensitivity of 88.24%and a specificity of 78.95%in diagnostics.
基金financial supports from National Natural Science Foundation of China(No.22377081)Shenzhen Science and Technology Program(No.JCYJ20230808105411023)+2 种基金Scientific Research Project of Education Department of Guangdong Province(No.2022ZDJS067)the Scientific Research Project of Hanshan Normal University(No.623012)the Education Research Project of Hanshan Normal University(Nos.E22061,521055).
摘要The overuse and improper disposal of tetracyclines raise significant environmental and public health concerns due to their persistent ecotoxicological effects.However,there is still a lack of simple,readily available,and effective method for simultaneously detecting multiple tetracyclines.Herein,we present a simple fluorescent sensor array for the detection and identification of multiple tetracyclines(including tetracycline,oxytetracycline,chlortetracycline,and doxycycline)based on host-guest recognitions between albumin(host)and tetracycline(guest).Upon entering the hydrophobic cavity of albumin,tetracycline exhibits a significant enhancement in its intrinsic fluorescence.The differential binding affinity of two albumins to four tetracyclines resulted in different fluorescent responses,creating distinct fluorescence patterns for each tetracycline.With the assistance of machine learning technique,including linear discriminant analysis(LDA)and hierarchical cluster analysis(HCA),this sensor array demonstrated the significant discrimination and classification capabilities for four common tetracyclines and their mixtures with 100%accuracy.Additionally,the array has been successfully applied to differentiate tetracyclines in real food samples.The spiked antibiotics in water sample were determined with a satisfactory recovery of 96.33%-106.5%.This work offers a simple but promising method for differentiating tetracycline antibiotics and presents a versatile strategy for sensor array design.
基金supported by the National Key Technology Research and Development Program of China (2023YFD1702200)the National Natural Science Foundation of China (42373080)+1 种基金the Major Science and Technology Project of Yunnan Province, China (202202AE090025)the Earmarked Fund for China Agriculture Research System (CARS-04)。
摘要Soil microbial-metabolite interactions influence crop productivity,yet their responses to long-term nutrient management in legume systems warrant further investigation.This study examined how fertilization and Bradyrhizobium inoculation reshape soybean rhizosphere fungal-metabolite networks to improve soil health.Through a decade-long field trial utilizing internal transcribed spacer(ITS) sequencing and liquid chromatography-mass spectrometry(LC-MS) metabolomics,four treatments were evaluated:no fertilizer application(CK);phosphorus and potassium fertilization(PK);PK chemical fertilizers combined with urea(PK+N);PK fertilization with Bradyrhizobium japonicum 5821 inoculation(PK+R).Results indicated that nitrogen fertilization increased fungal diversity at maturity and enhanced co-occurrence network complexity(displaying the highest node and edge counts),while Bradyrhizobium inoculation promoted stochastic assembly.Soil fungi exhibited notable correlations with 3-hydroxymethylantipyrine,chrysophanol,3,7-dihydroxyflavone and triethylamine.Metabolite profiling revealed nitrogen suppression of stress-resistant flavonoids(3-hydroxymethylantipyrine,chrysophanol,3,7-dihydroxyflavone),whereas Bradyrhizobium enhanced these key metabolites.KEGG enrichment identified tryptophan and caffeine metabolism as central during flowering-podding stage,coordinating nitrogen assimilation and defense responses.Additionally,the key metabolites correlated significantly with soil total nitrogen,organic matter,and available nitrogen.These findings reveal that Bradyrhizobium acts synergistically with fertilization to activate fungal-driven metabolic pathways,offering a microbiome-based approach to enhance nitrogen efficiency and reduce agrochemical dependency in soybean systems.
基金funded by the Ministe re des Ressources naturelles et des Forêts(project number 112332139 led by Jean-Daniel Sylvain and Guillaume Drolet)the National Science Foundation for Distin-guished Young Scholars of China(42425101)the State Scholarship Funding provided by the China Scholarship Council(202408350075)to conduct this research.
摘要Accurate modeling of carbon sequestration by forests requires scaling wood formation processes from trees to the landscape.The quantification of growth and carbon dynamics requires deep knowledge of the variability in xylem phenology among individuals.This study presents a comprehensive assessment of seasonal and individual variability in xylem phenology based on more than 800 balsam firs(Abies balsamea(L.)Mill.)monitored weekly across 33 plots from 2018 to 2022 in Montmorency Forest,Quebec,Canada.Wood microcores were collected from April to October to quantify the timings of cambial activity and xylem development on anatomical sections observed at high magnification under the microscope.The first enlarging cells appeared between late May and early June(day of the year(DOY)153-167),and cell-wall thickening ended in late August(DOY 223-238),resulting in a growing season of 63-79 days.Xylem production ranged from 27.4 to 47.9 radial cells.While the onset of xylogenesis was well synchronized among individuals,within 2 weeks,the cessation of growth showed a greater variability,reaching up to 3 weeks.This autumnal variability was positively correlated with wood production,as higher cambial activity increases the accumulation of xylem cells to be differentiated.Our findings provide empirical evidence that individual variability in growth cessation reflects the underlying heterogeneity in cambial activity among trees of the same stand.Our results demonstrate the role of xylem phenology,especially during the autumn,in shaping forest growth.The assessment of both seasonal and individual variability in phenology is an essential step to improve the representation of autumn processes in forest carbon models,which can help to reduce the uncertainty in predictions of boreal forest growth under current or future climate scenarios.
摘要宝鸡市滑坡灾害频发,但当前该区域滑坡编录数据样本较少,同时若仅采用滑坡点样本训练模型会导致模型的空间代表性不足,从而制约对该区域滑坡易发性评价的精度。针对此,结合卷积神经网络模型(convolutional neural net‐work,CNN)的局部特征提取优势和注意力机制Transformer的全局建模能力,提出一种融合Transformer与CNN的正样本缓冲滑坡易发性评价模型。依据滑坡规模设置90~130 m动态缓冲区扩展正样本,并综合考虑地形地貌、地质条件、水文气象和人类工程等选取13类滑坡影响因子,通过多重共线性分析后构建了滑坡评价体系。研究结果显示,采用缓冲区将随机森林、CNN、Transformer、Transformer-CNN模型四者的ROC曲线下的面积(area under the curve,AUC)从0.834、0.852、0.847、0.875分别提升至0.883、0.913、0.926、0.959。此外,Transformer-CNN相较CNN、Transformer,未缓冲时AUC分别从0.852、0.847提升至0.875,进行缓冲时分别从0.913、0.926提升至0.959;基于夏普利加性解释算法可解释性分析进一步揭示出岩性、年降雨、坡向三类因子对滑坡易发性预测贡献度最大,贡献度分别达0.55、0.47、0.43,且三者交互效应显著,为锁定区域滑坡高易发区提供了可量化的依据。
基金supported in part by the Fund of State Key Laboratory of Deep Oil and Gas,China University of Petroleum(East China)under Grant SKLDOG2024-ZYTS-02in part by the National Natural Science Foundation of China under Grant42274157+1 种基金in part by the Fundamental Research Funds for the Central Universities under Grant 24CX07004Ain part by the CNPC Innovation Fund under Grant 2024DQ02-0505。
摘要Seismic amplitude variation with offset(AVO)inversion is a cornerstone of oil and gas reservoir prediction,enabling the estimation of subsurface elastic parameters and characterization of stratigraphic interfaces.However,balancing inversion accuracy and computational efficiency remains a critical challenge.To address this,we propose a novel probabilistic AVO inversion framework integrating three key innovations.First,we derive a high-precision quadratic approximation for compressional(P-wave)reflectivity by retaining first-and second-order terms from the exact Zoeppritz equations through a perturbation strategy.This approach significantly enhances accuracy compared to conventional linear approximations,particularly in reflecting the true amplitude variation at large angles.Subsequently,to improve lateral continuity and stratigraphic resolution,we introduce an instantaneous phase constraint derived via the Hilbert transform.This constraint leverages phase sensitivity to seismic waveform coherence,ensuring geologically consistent interface characterization during stochastic inversion.Furthermore,we develop a hybrid Markov Chain Monte Carlo(MCMC)algorithm combining adaptive Gibbs sampling with the independent doubly adaptive rejection Metropolis sampling(IA2RMS)method.This framework efficiently samples high-dimensional posterior probability density functions(PDFs)of elastic pa rameters:Gibbs sampling gene rates adaptive proposal distributions,while IA2RMS accele rates Markov chain convergence through location-and scale-adjustable proposals.Numerical experiments and field seismic data demonstrate the robustness and feasibility of the proposed probabilistic AVO inversion method.
基金supported by the School of Digital Science,Universiti Brunei Darussalam,Brunei.
摘要Artificial Intelligence(AI)in healthcare enables predicting diabetes using data-driven methods instead of the traditional ways of screening the disease,which include hemoglobin A1c(HbA1c),oral glucose tolerance test(OGTT),and fasting plasma glucose(FPG)screening techniques,which are invasive and limited in scale.Machine learning(ML)and deep neural network(DNN)models that use large datasets to learn the complex,nonlinear feature interactions,but the conventional ML algorithms are data sensitive and often show unstable predictive accuracy.Conversely,DNN models are more robust,though the ability to reach a high accuracy rate consistently on heterogeneous datasets is still an open challenge.For predicting diabetes,this work proposed a hybrid DNN approach by integrating a bidirectional long short-term memory(BiLSTM)network with a bidirectional gated recurrent unit(BiGRU).A robust DL model,developed by combining various datasets with weighted coefficients,dense operations in the connection of deep layers,and the output aggregation using batch normalization and dropout functions to avoid overfitting.The goal of this hybrid model is better generalization and consistency among various datasets,which facilitates the effective management and early intervention.The proposed DNN model exhibits an excellent predictive performance as compared to the state-of-the-art and baseline ML and DNN models for diabetes prediction tasks.The robust performance indicates the possible usefulness of DL-based models in the development of disease prediction in healthcare and other areas that demand high-quality analytics.
摘要Herein,ratiometric fluorescence-based carbon dots(N-CDs)with blue emission were prepared by using simple one-step hydrothermal methods from benzimidazole and L-tryptophan as precursors.Dual emission peaks were observed at 356 and 442 nm under the excitation wavelength of 303 nm.Upon addition of sulfide ions(S2-),the fluorescence intensity at 442 nm decreased significantly,while that at 356 nm increased.The F442/F356 intensity ratio(where F356 and F442 refer to the fluorescence intensity at 356 and 442 nm,respectively)exhibited a linear relationship with the concentration of S2-(0-60.0μmol·L-1),and the detection limit was determined to be 0.076μmol·L-1.The fluorescence detection mechanism was ascribed to the static quenching effect.Furthermore,this fluorescence probe was successfully used for the determination of S2-in real samples with satisfactory recoveries.Finally,the analytical greenness metric for sample preparation(AGREEprep)and blue applicability grade index(BAGI)tools indicated the high sustainability of this platform.
摘要Quantum key distribution(QKD)has been widely deployed in practical applications after decades of development.However,the QKD system is easily affected by the external environment,especially free-space QKD.In this text,we examine two scenarios of free-space QKD in urban environments:satellite to ground and intercity.For satellite to ground QKD,the effects of stray light are analyzed.For intercity link,we discuss the influence of sea salt particles in coastal cities,and insoluble and soot particles in inland cities.Our findings indicate that using a telescope with a smaller field of view(FOV)and larger aperture diameters in satellite-to-ground QKD can effectively reduce errors induced by stray light.However,the diameter cannot be increased infinitely,when exceeding 0.8 m,the number of stray photons entering receiver rises rapidly and the quantum bits error rate(QBER)shows no significant reduction.For intercity QKD,the strength of extinction varies with relative humidity and aerosol particle radius,consequently altering channel transmittance.We investigate the impact of sea salt,insoluble particles,and soot on the key rate,finding that under the number density N=106m-3,sea salt exhibits the strongest impacts on key rate,especially when radius exceed 2.5μm.The impacts of insoluble particles are weaker and soot is the weakest,which can be ignored until N reaches 109m-3.For larger particle density,we can get higher key rate and further transmission distances in a soot-dominated environment.Our work could provide a valuable reference for the practical implementation of QKD in urban atmospheres.
基金supported by the Fund from Science,Technology and Innovation Commission of Shenzhen Municipality(Grant No.JCYJ20230807143712025)the National Natural Science Foundation of China(Grant No.62175077)。
摘要Physical layer security(PLS)has become a critical technique for the rapidly expanding communication network in the postquantum era,supporting superior secure communication rates with lower deployment cost.Typical PLS architecture follows the“key distribution before encrypted communication”paradigm,which causes redundant system structure and potential security issues.We propose an intrinsic physical layer secure communication architecture aided by a joint secure key distribution technique in this article.The architecture utilizes random time-varying polarization evolution induced by the fiber channel as the entropy source and estimated bit error rate information as the medium to implement an intrinsic key distribution scheme without requiring additional channels and complex devices.We realize simultaneous physical layer encrypted transmission and error-free joint secure key distribution(SKD)based on this architecture.The experimental demonstration verifies the feasibility of the scheme.We believe the highly integrated secure communication architecture with multiple guaranteed security measures may not only provide a feasible,low-cost solution for the deployment of the SKD system in a variety of communication scenarios,but also propose a“key distribution within encrypted communication”paradigm for future PLS solutions.